Two dicarboxylic acids were prepared by alkylation of 4-hydroxycinammic acid with 1,6-dibromohexane or 1,12-dibromododecane. The dichlorides of these dicarboxylic acids were polycondensed with mixtures of isosorbide and methylhydroquinone. All copolyesters then obtained showed nematic schlieren textures. Furthermore, three dicarboxylic acids were synthezised by alkylation of 4-hydroxycinammic acid with the ditosylates of di-, tri-, and tetraethylene glycol. Numerous copolyesters were prepared from the dicarboxylic acids and mixtures of isosorbide with methyl-, tert-butyl-, or phenylhydroquinone. Also 2,7-dihydroxynaphthalene was used as a comonomer. Almost all resulting copolyesters were cholesteric, and nearly 50% of them were capable of forming a Grandjean texture. The photochemical behavior of selected copolyesters was studied in solution in spin-coated films and in films with Grandjean texture. Depending on the reaction conditions, photo-cross-linking by 2 + 2 cycloaddition competed more or less successfully with the photo-Fries rearrangement and with the photoisomerization. UV irradiation (at 313 nm) of oriented films in the cholesteric melt caused disappearance of the Grandjean texture. However, irradiation below the glass-transition temperature caused stabilization of the Grandjean texture by photo-cross-linking.