화학공학소재연구정보센터
Langmuir, Vol.16, No.4, 1650-1654, 2000
Sedimentation of concentrated charged spheres at low surface potentials
lThe sedimentation of concentrated charged spherical particles in an electrolyte solution is investigated theoretically for an arbitrarily thick double layer taking the effect of double-layer polarization into account. We show that the ratio E*/U* (=scaled sedimentation potential per scaled sedimentation velocity) is a constant if kappa a is either very small or very large, kappa and a being respectively the reciprocal Debye length and the radius of a particle. The variation of E*/U* as a function of kappa a has a minimum at a medium kappa a. This minimum increases with the increase in particle concentration. The scaled sedimentation velocity approaches a constant if kappa a is small, and its variation as a function of kappa a has a maximum at a medium kappa a. This maximum decreases with the decrease in particle concentration.