Langmuir, Vol.15, No.6, 2149-2151, 1999
Morphological characterization of H aggregates in Langmuir-Blodgett films of pyridinium-dicyanomethanide dyes
We investigated the aggregation of the pyridinium-dicyanomethanide dye 4 -[5-(dicyanomethanido)thien-2-yl]-N-(n-hexadecyl)pyridinium (C16H33-PDCNT), in transferred films obtained with the Langmuir-Blodgett (LB) technique; this behavior is an example for the formation of H* aggregates, which show strongly blue-shifted and sharp electronic absorption bands. Surface pressure-area isotherms are reported at T = 291 K. LB films were investigated by UV-vis spectroscopy and optical and atomic force microscopy in order to obtain information about the molecular structure of the aggregates. The molecule strongly absorbs in the visible region because of a charge-transfer band; the sharp peak at 422 nm is attributed to the formation of H* aggregates.
Keywords:SQUARAINE