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Applied Biochemistry and Biotechnology, Vol.61, No.3, 411-422, 1996
Reaction-Kinetics of the Esterification of Lauric Acid in Isooctane Using an Immobilized Biocatalyst
The kinetics of the esterification of lauric acid with geraniol catalyzed by a commercially immobilized lipase preparation from Mucor miehei, Lipozyme, was studied in well-stirred flasks under conditions of no external mass transfer limitations. It was shown that the reaction is inhibited by lauric acid and the reaction mechanism can be described as a Ping-Pong Bi-Bi with Dead-End inhibition caused by lauric acid.
Keywords:LIPASE-CATALYZED-HYDROLYSIS;CARBOXYLIC-ESTER HYDROLASE;NORMAL-HEXANE;MECHANISM;TRANSESTERIFICATION;ACETATE