Journal of Vacuum Science & Technology A, Vol.17, No.3, 936-938, 1999
Different effect of annealing temperature on resistivity for stoichiometric, W rich, and N rich tungsten nitride films
The effect of the annealing temperature on the resistivity for stoichiometric (W2N), W rich (x<0.5), and N rich (x>0.5) tungsten nitride films (WNx) is different. The resistivity of as-deposited W2N is about 230 mu Omega cm and it increases slightly and then decreases with increasing the annealing temperature up to 900 degrees C. However, for the W rich WNx whose initial resistivity before annealing is around 145 mu Omega cm, the resistivity monotonically decreases with the annealing temperature increasing from 600 to 900 degrees C, As to N rich WNx whose initial resistivity is as high as 3000-5000 mu Omega cm, though the resistivity must decrease after annealing at 600-750 degrees C, it irregularly varies at the higher temperature range of 750-900 degrees C. The different annealing temperature dependence of the resistivity can be explained by considering the nitrogen desorption, conversion of WNx to pure W, and cracking of WNx films.
Keywords:DIFFUSION-BARRIERS