화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.103, 216-221, November, 2021
DOI10.1016/j.jiec.2021.07.034  Export Citation
Accelerated CO2 transport by synergy effect of ionic liquid and Zn particles
Seung Yeon Rhyu1, and Sang Wook Kang1, 2, †
  • 1Department of Chemistry, Sangmyung University, Seoul 03016, Republic of Korea
  • 2Department of Chemistry and Energy Engineering, Sangmyung University, Seoul 03016, Republic of Korea
E-mail:
In this experiment, an ionic liquid (BMIMBF4) was used to prepare a composite membrane containing ZnO nanoparticles. Our previous study indicated that a composite membrane composed of ZnO and the ionic liquid (BMIMBF4) showed high CO2/N2 separation performance with a GPU of 101 and a selectivity of 42.1. The oxide layer of ZnO nanoparticles with the imidazolium ring of ionic liquid (BMIMBF4) increased the solubility of CO2 and acted as a barrier for N2, leading to an overall improvement in the performance. However, the liquid film was absorbed into support over time and became thickened, leading to instability. In order to solve this problem, a solid polymer composite film was manufactured and investigated as a solution. The polymer PEBAX2533 was used as a polymer matrix to produce a composite membrane capable of showing both high separation performance and long-term stability.
Keywords:CO2 behavior;ZnO nanoparticles;PEBAX-2533;Ionic liquid
  1. Kumar R, Zhang C, Itta AK, Koros WJ, J. Membr. Sci., 583, 9 (2019)
  2. CO2 Emission from Fuel Combustion Highlights 2018 Edition, International Energy Agency (2018).
  3. Benajes J, Garcia A, Serrano JM, Boggio SM, Transp. Eng., 1 (2020)
  4. Yi Q, Zhao YJ, Huang Y, Wei GQ, Hao YH, Feng J, Mohamed U, Pourkashanian M, Nimmo W, Li WY, Appl. Energy, 225, 258 (2018)
  5. Duan LQ, Xia K, Feng T, Jia SL, Bian J, Energy, 117, 578 (2016)
  6. Saqib S, Rafiq S, Muhammad N, Khan AL, Mukhtar A, Mellon NB, Man Z, Nawaz MH, Jamil F, Ahmad NM, J. Nat. Gas Sci. Eng., 73 (2020)
  7. Zhang J, Xin Q, Li X Yun M, Xu R, Wang S, Li Y, Lin L, Ding X, Ye H, Zhang Y, J. Membr. Sci., 570-571, 343 (2019)
  8. Kenarsari SD, Yang D, Jiang G, Zhang S, Wang J, Russell AG, Wei Q, Fan M, RSC Adv., 3, 22739 (2013)
  9. Gomes CDN, Jacquet O, Villiers C, Thuery P, Ephritikhine M, Cantat T, Angew. Chem.-Int. Edit., 51, 187 (2012)
  10. Li G, Cui P, Wang Y, Liu Z, Zhu Z, Yang S, Energy, 191 (2020)
  11. Yoon KW, Kang SW, Chem. Eng. J., 334, 1749 (2018)
  12. Du N, Park HB, Cin MMD, Guiver MD, Energy Environ. Sci., 5, 7306 (2012)
  13. Chuah CY, Lim W, Samarasinghe SASC, Sethunga GSMDP, Bae TH, Microporous Mesoporous Mater., 290 (2019)
  14. Zheng WJ, Ding R, Yang K, Dai Y, Yan XM, He GH, Sep. Purif. Technol., 214, 111 (2019)
  15. Li T, Pan Y, Peinemann KV, Lai Z, J. Membr. Sci., 425-426, 235 (2013)
  16. Anjum MW, Vermoortele F, Khan AL, Bueken B, Vos DED, Vankelecom IFJ, ACS Appl. Mater. Interfaces, 7, 25193 (2015)
  17. Moermans B, Beuckelaer WD, Vankelecom IFJ, Ravishankar R, Martens JA, Jacobs PA, Chem. Commun, 2467 (2000).
  18. Banerjee R, Furukawa H, Britt D, Knobler C, O’Keeffe M, Yaghi OM, J. Am. Soc., 131, 3875 (2009)
  19. Majumdar S, Tokay B, Gil VM, Campbell J, Munoz RC, Ahmad MZ, Fila V, Sep. Purif. Technol., 238 (2020)
  20. Sun JJ, Li QQ, Chen GN, Duan JG, Liu GP, Jin WQ, Sep. Purif. Technol., 217, 229 (2019)
  21. Bahamon D, Diaz-Marquez A, Gamallo P, Vega LF, Chem. Eng. J., 342, 458 (2018)
  22. Shahid S, Nijmeijer K, J. Membr. Sci., 459, 33 (2014)
  23. Liu B, Li D, Yao J, Sun H, Sep. Purif. Technol., 239 (2020)
  24. Tang WY, Lou H, Li YF, Kong XB, Wu YH, Gu XH, J. Membr. Sci., 581, 93 (2019)
  25. Yan XR, Anguille S, Bendahan M, Moulin P, Sep. Purif. Technol., 222, 230 (2019)
  26. Hasib-ur-Rahman M, Siaj M, Larachi F, Chem. Eng. Process., 49(4), 313 (2010)
  27. Hossain I, Al Munsur A, Choi O, Kim TH, Sep. Purif. Technol., 224, 180 (2019)
  28. Du N, Park HD, Dal-Cin MM, Guiver MD, Energy Enviorn. Sci., 5, 7306 (2012)
  29. Safarpour M, Arefi-Oskoui S, Khataee A, J. Ind. Eng. Chem., 82, 31 (2020)
  30. Wang S, Li X, Wu H, Tian Z, Xin Q, He G, Peng D, Chen S, Yin Y, Jiang Z, Guiver MD, Energy Enviorn. Sci., 9, 1863 (2016)
  31. Roy S, Ntim SA, Mitra S, Sirkar KK, J. Membr. Sci., 375(1-2), 81 (2011)
  32. Du N, Park HB, Dal-Cin MM, Guiver MD, Energy Environ. Sci., 5, 7306 (2012)
  33. Li SG, Falconer JL, Noble RD, Adv. Mater., 18(19), 2601 (2006)
  34. Wiles C, Watts P, Jaswell SJ, Tetrahedron Lett., 47, 5261 (2006)
  35. Lee WG, Kang SW, Chem. Eng. J., 252, 262 (2014)
  36. Chae IS, Hong GH, Song DH, Kang YS, Kang SW, Macromol. Res., 27(3), 250 (2019)
  37. Kim HY, Kang SW, Sci. Rep., 9, 16563 (2019)
  38. Yoon KW, Kim H, Kang YS, Kang SW, Chem. Eng. J., 320, 50 (2017)
  39. Sun H, Gao W, Zhang Y, Cao X, Bao S, Li P, Kang Z, Niu QJ, React. Funct. Polym., 147, 104465 (2020)
  40. Mohammed SA, Nasir AM, Aziz F, Kumar G, Sallehhudin W, Jaafar J, Lau WJ, Yusof N, Salleh WNW, Ismail AF, Sep. Purif. Technol., 223, 142 (2019)
  41. Song C, Li R, Fan Z, Liu Q, Zhang B, Kitamura Y, Sep. Purif. Technol., 238 (2020)
  42. Meshkat S, Kaliaguine S, Rodrigue D, Sep. Purif. Technol., 235 (2020)
  43. Chen BC, Wan C, Kang XT, Chen MQ, Zhang CF, Bai YX, Dong LL, Sep. Purif. Technol., 223, 113 (2019)
  44. Jeon HS, Kang SW, Polym. Compos. (2018).
  45. Park HB, Kim CK, Lee YM, J. Membr. Sci., 204(1-2), 257 (2002)
  46. Solimando X, Babin J, Arnal-Herault C, Wang M, Barth D, Roizard D, Doillon-Halmenschlager JR, Poncot M, Royaud I, Alcouffe P, David L, Jonquieres A, Polymer, 131, 56 (2017)
  47. Khalilinejad I, Kargari A, Sanaeepur H, Chem. Pap. DOI 10.1007/s11696-016-0084-5.
  48. Rhyu SY, Kang SW, J. Ind. Eng. Chem. (2020).
  49. Vakili E, Semsarzadeh MA, Ghalei B, Khoshbin M, Nasiri H, Silicon, 8(1), 75 (2016)
  50. Gao J, Mao H, Jin H, Chen C, Feldhoff A, Li Y, Microporous Mesoporous Mater., 297 (2020)
  51. Han Y, Ho WSW, J. Polym. Eng., 1 (2019)