화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.103, 42-48, November, 2021
DOI10.1016/j.jiec.2021.05.014  Export Citation
Gasification investigations of coal and biomass blends for high purity H2 production with carbon capture potential
Dingkun Yuan, Kang Zhang1, †, Lijian Wang2, Lingfeng Jin1, Xutao Guo1, and Guangxue Zhang
  • The Institute for Energy Engineering, China Jiliang University, Hangzhou 310000, PR China
  • 1State Grid Zhejiang Electric Power Research Institute, Hangzhou 310014, PR China
  • 2Zhejiang Institute of Metrology, Hangzhou 310000, PR China
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Biomass is carbon-neutral and has the carbon-negative potential if combined with carbon capture and storage (CCS). This study investigated the thermochemical conversion to high-purity hydrogen of a typical lignite (BYH) and seaweed biomass (BS) with carbon capture in a designed fixed-bed reactor at moderate conditions (1 atm, 873 K). High-purity hydrogen of 486.91-801.5 ml/g-blends with suppressed CO2 formation was produced in the alkaline gasification. The alkali can decompose the coal/biomass molecular structures, in-situ capture CO2 and control the gases to high-purity H2 (80.1%-93.2%). The synergistic effect of coal and biomass changes the gas evolution behaviors and impacts the chemical structures of the char. The abundant SiO2 and Al2O3 in the coal can inhibit the catalytic activities of earth alkali metals in the biomass, but not much. These results are significant to the future development of low-carbon renewable energy techniques.
Keywords:Co-gasification;Hydrogen production;Carbon capture;Synergistic effect
  1. Zhao ZH, Wang RK, Ge LC, Wu JH, Yin QQ, Wang CB, Energy, 168, 609 (2019)
  2. Hu P, Zhang Y, Liu T, Huang J, Yuan Y, Zheng Q, J. Ind. Eng. Chem., 45, 241 (2017)
  3. Xincheng T, Shengli N, Shuang Z, Xiangyu Z, Ximing L, Hewei Y, Chunmei L, Kuihua H, J. Ind. Eng. Chem., 77, 432 (2019)
  4. Adamu S, Razzak SA, Hossain MM, J. Ind. Eng. Chem., 64, 467 (2018)
  5. Farooq A, Moogi S, Jang SH, Kannapu HPR, Valizadeh S, Ahmed A, Lam SS, Park YK, J. Ind. Eng. Chem., 94, 336 (2021)
  6. Frau C, Ferrara F, Orsini A, Pettinau A, Fuel, 152, 138 (2015)
  7. Liu L, Cao Y, Liu QC, Fuel, 146, 103 (2015)
  8. Al-Zareer M, Dincer I, Rosen MA, Int. J. Hydrog. Energy, 45(20), 11577 (2020)
  9. Chu S, Majumdar A, Nature, 488(7411), 294 (2012)
  10. Sikarwar VS, Zhao M, Clough P, Yao J, Zhong X, Memon MZ, Shah N, Anthony EJ, Fennell PS, Energy Environ. Sci., 9, 2939 (2016)
  11. Zhao X, Zhou H, Sikarwar VS, Zhao M, Park AHA, Fennell PS, Shen L, Fan LS, Energy Environ. Sci., 10, 1885 (2017)
  12. Zhang K, Kim WJ, Park AHA, Nat. Commun., 11, 3783 (2020)
  13. Zhang K, Ouassil N, Campo CAO, Rim G, Kim WJ, Park AHA, J. Ind. Eng. Chem., 85, 219 (2020)
  14. Howaniec N, Smolinski A, Stanczyk K, Pichlak M, Int. J. Hydrog. Energy, 36(22), 14455 (2011)
  15. Tursun Y, Xu SP, Wang C, Xiao YH, Wang GY, Fuel Process. Technol., 141, 61 (2016)
  16. Yan LB, Yue GX, He BS, Bioresour. Technol., 205, 133 (2016)
  17. Nurdiawati A, Zaini IN, Irhamna AR, Sasongko D, Aziz M, Renew. Sust. Energ. Rev., 112, 369 (2019)
  18. Liu Q, Hu C, Peng B, Liu C, Li Z, Wu K, Zhang H, Xiao R, Energy Conv. Manag., 199, 111951 (2019)
  19. Darmawan A, Ajiwibowo MW, Yoshikawa K, Aziz M, Tokimatsu K, Appl. Energy, 219, 290 (2018)
  20. Stonor MR, Chen JGG, Park AHA, Int. J. Hydrog. Energy, 42(41), 25903 (2017)
  21. Stonor MR, Ferguson TE, Chen JG, Park AHA, Energy Environ. Sci., 8, 1702 (2015)
  22. Shahbaz M, Yusup S, Al-Ansari T, Inayat A, Inayat M, Zeb H, Alnarabiji MS, Energy Fuels, 33(11), 11318 (2019)
  23. Perander M, DeMartini N, Brink A, Kramb J, Karlstrom O, Hemming J, Moilanen A, Konttinen J, Hupa M, Fuel, 150, 464 (2015)
  24. Kirtania K, Axelsson J, Matsakas L, Christakopoulos P, Umeki K, Furusjo E, Energy, 118, 1055 (2017)
  25. Wang SQ, Tang YG, Schobert HH, Guo YA, Su YF, Energy Fuels, 25(12), 5672 (2011)
  26. Alcaniz-Monge J, Cazorla-Amoros D, Linares-Solano A, Fuel, 80, 41 (2001)
  27. Zhao M, Cui X, Ji G, Zhou H, Vuppaladadiyam AK, Zhao X, ACS Sustain. Chem. Eng., 7, 1202 (2018)
  28. Zhang Kang, Li Yan, Wang Zhihua, Li Qian, Whiddon Ronald, He Yong, Cen Kefa, Fuel, 185, 701 (2016)
  29. Secer A, Kucet N, Faki E, Hasanoglu A, Int. J. Hydrog. Energy, 43(46), 21269 (2018)
  30. Lv JW, Ao XQ, Li Q, Cao Y, Chen QL, Xie Y, Bioresour. Technol., 283, 59 (2019)
  31. Saxena SK, Int. J. Hydrog. Energy, 28(1), 49 (2003)
  32. Umeki K, Haggstrom G, Bach-Oller A, Kirtania K, Furusjo E, Energy Fuels, 31(5), 5104 (2017)
  33. Furusjo E, Ma CY, Ji XY, Carvalho L, Lundgren J, Wetterlund E, Energy, 157, 96 (2018)