Reinforcing Efficiency of Pyrolyzed Spent Coffee Ground in Styrene-Butadiene Rubber

Supparoek Boopasiri; Pongdhorn Sae-Oui; Sirilug Lundee; Sukanya Takaewnoi; Chomsri Siriwong

Macromolecular Research, Vol.29, No.9, 597-604, September, 2021

DOI10.1007/s13233-021-9072-x Export Citation

Reinforcing Efficiency of Pyrolyzed Spent Coffee Ground in Styrene-Butadiene Rubber

Supparoek Boopasiri, Pongdhorn Sae-Oui¹, Sirilug Lundee, Sukanya Takaewnoi, and Chomsri Siriwong^†

Materials Chemistry Research Center (MCRC) and Center of Excellence for Innovation in Chemistry (PERCH-CIC), Department of Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen, 40002, Thailand
¹National Metal and Materials Technology Center (MTEC), National Science and Technology Development Agency (NSTDA), Thailand Science Park, Pathum Thani, 12120, Thailand

E-mail:

This research aimed to study the reinforcing efficiency of pyrolyzed spent coffee ground (SCG) in styrene-butadiene rubber (SBR). The SCG was initially treated at elevated temperatures of 700℃ and 900℃ (under nitrogen gas) before being characterized by various techniques, e.g., particle size analysis, Fourier transform infrared spectroscopy, X-ray diffraction and scanning electron microscopy. After being added into SBR, properties of the rubber compounds and vulcanizates were determined. The results showed that pyrolysis of SCG at 700℃ and 900℃ significantly reduced the average particle size from 39.8 μm to 27.3 μm and 25.3 μm, respectively. The addition of pyrolyzed SCG into SBR resulted in the increases of both rubber-filler interaction, as evidenced from the increase of bound rubber content, and crosslink density, leading to the improvement of mechanical properties of the rubber vulcanizates when compared with the addition of untreated SCG.

Keywords:rubber;spent coffee grounds;reinforcement;pyrolysis;mechanical properties

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[2] Niranjan R, Thakur AK, Front. Immunol., 8, 763 (2017)

[3] Mokhothu TH, John MJ, Handb. Compos. Renewable Mater., 1, 243 (2017)

[4] Isikgor FH, Becer CR, Polym. Chem., 6, 4497 (2015)

[5] Gaidukova G, Platnieks O, Aunins A, Barkane A, Ingrao C, Gaidukovs S, RSC Adv., 11, 18580 (2021)

[6] Barana D, Orlandi M, Salanti A, Castellani L, Hanel T, Zoia L, Ind. Crop. Prod., 141, 111822 (2019)

[7] Bodirlau R, Teaca CA, Spiridon I, Composites, Part B, 44, 575 (2013)

[8] Mansor MK, Ali RC, Adv. Mater. Res., 1133, 593 (2016)

[9] Ghani H, Abd Karim SF, Ramli R, Musa M, Jaapar J, Key Eng. Mater., 797, 249 (2019)

[10] Azwar E, Hakkarainen M, ISRN Polym. Sci., 2012, 463298 (2012)

[11] Ruangudomsakul W, Ruksakulpiwat C, Yupaporn R, Adv. Mater. Res., 747, 371 (2013)

[12] Santos RD, Agostini D, Cabrera F, Aparecido E, Reis P, Ruiz M, Budemberg E, Teixeira S, Job A, Polimeros, 24, 646 (2014)

[13] Yang J, Ching YC, Chuah CH, Polymers, 11, 751 (2019)

[14] Tun MM, Raclavska H, Juchelkova D, Ruzickova J, Safar M, Strbova K, Gikas P, J. Environ. Manage., 275, 111204 (2020)

[15] Counts TW, Number of Coffee Bags Produced.

[16] Blinova L, Sirotiak M, Bartosova A, Soldan M, Res. Pap. - Fac. Mater. Sci. Technol., Slovak Univ. Technol., 25, 91 (2017).

[17] Mussatto SI, Ballesteros LF, Martins S, Teixeira JA, Sep. Purif. Technol., 83, 173 (2011)

[18] Caetano SN, Silva VSM, Mata TM, Chem. Eng. Trans., 26, 267 (2012)

[19] Kante K, Nieto-Delgado C, Rangel-Mendez JR, Bandosz TJ, J. Hazard. Mater., 201-202, 141 (2012)

[20] Kim MS, Min HG, Koo N, Park J, Lee SH, Bak GI, Kim JG, J. Environ. Manage., 146, 124 (2014)

[21] Fiol M, Escudero C, Villaescusa I, Sep. Sci. Technol., 43(3), 582 (2008)

[22] Somnuk K, Eawlex P, Prateepchaikul G, Agric. Nat. Resour., 51, 181 (2017)

[23] Passadis K, Fragoulis V, Stoumpou V, Novakovic J, Barampouti EM, Mai S, Moustakas K, Malamis D, Loizidou M, Waste Biomass Valorization, 11, 5295 (2020)

[24] Campos-Vega R, Loarca-Pina G, Vergara-Castaneda HA, Oomah BD, Trends Food Sci. Technol., 45, 24 (2015)

[25] Ballesteros LF, Teixeira JA, Mussatto SI, Food Bioprocess Technol., 7, 3493 (2014)

[26] Suaduang N, Ross S, Ross GM, Pratumshat S, Mahasaranon S, Mater. Today: Proc., 17, 2104 (2019)

[27] Sung SH, Chang Y, Han J, Carbohydr. Polym., 169, 495 (2017)

[28] Kanai N, Honda T, Yoshihara N, Oyama T, Naito A, Ueda K, Kawamura I, Cellulose, 27, 5017 (2020)

[29] Garcia-Garcia D, Carbonell A, Samper MD, Garcia-Sanoguera D, Balart R, Compos. Part B, 78, 256 (2015)

[30] Siriwong C, Boopasiri S, Jantarapibun V, Kongsook B, Pattanawanidchai S, Sae-Oui P, J. Appl. Polym. Sci., 135, 46060 (2018)

[31] Dzulkifli AI, Said CMS, Han CC, Mohd AF, Adv. Mater. Res., 1134, 75 (2015)

[32] Prudenziati M, Sens. Actuators A-Phys., 25, 227 (1990)

[33] Nguyen VT, Nguyen TB, Chen CW, Hung CM, Vo TDH, Chang JH, Dong CD, Bioresour. Technol., 284, 197 (2019)

[34] Jagdale P, Ziegler D, Rovere M, Tulliani JM, Tagliaferro A, Sensors, 19, 801 (2019)

[35] Mendez A, Cardenas-Aguiar E, Paz-Ferreiro J, Plaza C, Gasco G, Biol. Agric. Hortic., 33, 40 (2017)

[36] Brewer CE, Chuang VJ, Masiello CA, Gonnermann H, Gao XD, Dugan B, Driver LE, Panzacchi P, Zygourakis K, Davies CA, Biomass Bioenerg., 66, 176 (2014)

[37] Ding W, Dong X, Ime IM, Gao B, Ma LQ, Chemosphere, 105, 68 (2014)

[38] Yuan JH, Xu RK, Zhang H, Bioresour. Technol., 102(3), 3488 (2011)

[39] Nguyen VT, Nguyen TB, Chen CW, Hung CM, Huang CP, Dong CD, Bioresour. Technol., 292, 121954 (2019)

[40] Medalia AI, Richards LW, J. Colloid Interface Sci., 40, 233 (1972)

[41] Hofmann W, Rubber Technology Handbook, Hanser, Munich, 1996.

[42] Quosai P, Anstey A, Mohanty A, Misra M, R. Soc. Open Sci., 5, 171970 (2018)

[43] Das O, Sarmah AK, Zujovic Z, Bhattacharyya D, Sci. Total Environ., 550, 133 (2016)

[44] Pusceddu E, Int. J. New Technol. Res., 3, 39 (2017)

[45] Kato A, Ikeda Y, Tsushi R, Kokubo Y, Kojima N, Colloid Polym. Sci., 291, 2101 (2013)