Zein.sodium alginate based microcapsules for essence controlled releasing coating as leather finishes

Qunna Xu; Zhongxue Bai; Jianzhong Ma; Yuxi Yang; Mengchen Huang

Journal of Industrial and Engineering Chemistry, Vol.100, 204-211, August, 2021

DOI10.1016/j.jiec.2021.05.022 Export Citation

Zein.sodium alginate based microcapsules for essence controlled releasing coating as leather finishes

Qunna Xu^{1, 2, †}, Zhongxue Bai^{1, 2}, Jianzhong Ma^{1, 2, †}, Yuxi Yang^{1, 2}, and Mengchen Huang^{1, 2}

¹College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi’an 710021, China
²National Demonstration Center for Experimental Light Chemistry Engineering Education, Xi’an 710021, China

E-mail:,

Currently the development and application of leather are strongly limited by the peculiar smells of the leather itself and the chemical residues in the leather. However, traditional finishing materials containing essences have a short release period, but also weaken the mechanical properties of the coating. Herein, we first report a route of crafting essence controlled releasing coatings as leather finishes comprising zein.sodium alginate microcapsules loaded with Artemisia argyi essence (AAE@Z-SMs) and casein modified by caprolactam (Ca-Cpl), of which AAE@Z-SMs was prepared by anti solvent precipitation technique before physically blended with Ca-Cpl to prepare composite coating. The results showed that the average particle size of AAE@Z-SMs was about 5.7 mm, and the accumulative release rate of essence in AAE@Z-SMs was 48.3% after continuous release for 120 h. Besides, the AAE@Z-SMs+Ca Cpl film is transparent and has good flexibility, with pores and microspheres uniformly distributed inside. Moreover, the inhibition zones of the leather samples finished by AAE@Z-SMs+Ca-Cpl against Escherichia coli (E. coli) (1st d) and Staphylococcus aureus (S. aureus) (2nd d) were 2.6 cm and 4.2 cm respectively, which hardly changed after continuing culture for 2 days. Moreover, expected sanitary, mechanical and antibacterial properties of the leather finished could be given by AAE@Z-SMs based composites. This study provides a feasible way to prepare composite coating materials with functionality based on natural protein, polysaccharide and plant essence.

Keywords:Zein;Artemisia argyi essence;Sodium alginate;Composite coating;Leather

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[1] Fan QQ, Ma JZ, Xu QN, J. Leather Sci. Eng., 1, 1 (2019)

[2] Xu QN, Carmen GD, Fan QQ, Guo CS, Zhang J, Colloids Surf. B: Biointerfaces, 128, 181 (2015)

[3] Kothandam R, Pandurangan M, Jayavel R, Gupta S, J Cluster Sci., 27, 1263 (2016)

[4] Zhao J, Li Y, Sheng J, Wang X, Liu L, Yu J, Ding B, ACS Appl. Mater. Interfaces, 9, 29302 (2017)

[5] Lu Z, Chen Z, Guo Y, Ju Y, Liu Y, Feng R, Xiong C, Ober CK, Dong L, ACS Appl. Mater. Interfaces, 10, 9718 (2018)

[6] Li SP, Kowarski CR, Feld KM, Grim WM, Drug Dev. Commun., 14, 353 (2008)

[7] Deng Z, Wang S, Zhou B, Li J, Zhou P, Li B, Liang H, Food Res. Int., 128, 108867 (2019)

[8] Mazumder MAJ, Burke NAD, Shen F, Potter MA, Stover HDH, Biomacromolecules, 10(6), 1365 (2009)

[9] Chang C, Varankovich N, Nickerson MT, Food Chem., 212, 264 (2016)

[10] Kaushik P, Rawat K, Aswal VK, Kohlbrecher J, Bohidar HB, Carbohydr. Polym., 224, 115150 (2019)

[11] Fan QQ, Ma JZ, Xu QN, Wang J, Ma YX, Ind. Eng. Chem. Res., 57(18), 6171 (2018)

[12] Song J, Sun C, Zhang J, Xiong Z, Fang Y, J. Agric. Food Chem., 68, 13138 (2020)

[13] Yu Y, Li H, Liu C, Zhang S, Xu Y, Wang D, J. Agric. Food Chem., 67, 11977 (2019)

[14] Jiang Y, Wang D, Li F, Li D, Huang Q, Int. J. Biol. Macromol., 148, 1280 (2020)

[15] da Rosa CG, de Melo APZ, Sganzerla WG, Machado MH, Nunes MR, Maciel MVDOB, Bertoldi EC, Barreto PLM, Food Hydrocolloids, 99, 105339 (2020)

[16] Chen HQ, Zhang Y, Zhong QX, J. Food Eng., 144, 93 (2015)

[17] Chen S, Li Q, McClements DJ, Han Y, Dai L, Mao L, Gao Y, Food Hydrocolloids, 99, 105334 (2020)

[18] Dai L, Zhou H, Wei Y, Gao Y, McDlements DJ, Food Hydrocolloids, 93, 342 (2019)

[19] De Boer FY, Imhof A, Velikov KP, Food Chem.: X, 100071 (2019).

[20] Ma JZ, Xu QN, Gao DG, Zhou JH, Zhang J, Polym. Degrad. Stabil., 97, 1545 (2012)

[21] Weissmueller NT, Lu HD, Hurley A, Prud'homme RK, Biomacromolecules, 17(11), 3828 (2016)

[22] Wang YN, Ma JZ, Xu QN, Zhang J, Mater. Des., 113, 240 (2017)

[23] Fu F, Li L, Li uL, Cai J, Zhang Y, Zhou J, Zhang L, ACS Appl. Mater. Interfaces, 7, 2597 (2015)

[24] Liu Q, Chen J, Qin Y, Jiang B, Zhang T, Int. J. Biol. Macromol., 158, 461 (2020)

[25] Wei Y, Sun C, Dai L, Zhan X, Gao Y, Food Hydrocolloids, 81, 149 (2018)

[26] Wei Y, Yu Z, Lin K, Sun C, Dai L, Yang S, Mao L, Yuan F, Gao Y, Food Hydrocolloids, 95, 336 (2019)

[27] Teng MJ, Wei YS, Hu TG, Zhang Y, Wu H, J. Food Eng., 281, 109993 (2020)

[28] Bortoletto-Santos R, Plotegher F, Roncato V, Majaron RF, Majaron VF, Polito WL, J. Agric. Food Chem., 66, 9582 (2018)

[29] Li H, Wang D, Liu C, Zhu J, Fan M, Sun X, Wang T, Xu Y, Cao Y, Food Hydrocolloids, 87, 342 (2019)

[30] Sahu A, Kasoju N, Goswami P, Bora U, J. Biomater. Appl., 25, 619 (2011)

[31] Kitaura R, Onoyama G, Sakamoto H, Matsuda R, Noro SC, Kitagawa S, Angew. Chem.-Int. Edit., 43, 26848 (2004)

[32] Ramos M, Beltran A, Peltzer M, Valente AMJ, LWT Food Sci. Technol. 58.2, 470 (2014).

[33] Perazzo FF, Carvalho JCT, Carvalho J, Rehder V, Pharmacol. Res., 48, 497 (2003)

[34] Ozek G, Suleimen Y, Tabanca N, Doudkin R, Gorovoy PG, Goger F, Wedge DE, Ali A, Khan IA, Baser KH, Rec. Nat. Prod., 8, 242 (2014)

[35] Liu C, Yin Q, Li X, Hao LF, Zhang W, Bao Y, Ma JZ, Adv. Compos. Hybrid Mater., 18, 1 (2021)

[36] Yang Z, Zeng Z, Xiao Z, Ji H, Flavour Fragance J., 29, 114 (2014)