화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.99, 179-186, July, 2021
DOI10.1016/j.jiec.2021.04.026  Export Citation
Elevated surface plasmon resonance sensing sensitivity of Au-covered silica sphere monolayer prepared by Langmuir.Blodgett coating
Baeck B. Choi1, 2, †, Bethy Kim3, Yiqi Chen1, Sung Jong Yoo4, Younghyun Cho5, †, and Peng Jiang1, †
  • 1Department of Chemical Engineering, University of Florida, Gainesville, FL 32611, USA
  • 2Energy and Environment Laboratory, Korea Electric Power Corp. Research Institute, Daejeon 34056, Republic of Korea
  • 3Department of Chemistry, University of Florida, University of Florida, USA
  • 4Fuel Cell Research Center, Korea Institute of Science and Technology (KIST), Seoul 02792, Republic of Korea
  • 5Department of Energy Systems Engineering, Soonchunhyang University, Asan 31538, Republic of Korea
E-mail:, ,
The colloidal Langmuir.Blodgett coating process is used to fabricate Au-covered silica sphere monolayer (Au film over silica nanosphere (AuFON)) and study the effects of silica diameter on surface plasmon resonance (SPR) sensing sensitivity. The resulting hexagonal close-packed (HCP) monolayers are prepared with silica sphere diameters of 200, 400, 700, and 1000 nm. In SPR sensing applications, the optical properties of Au-covered silica sphere monolayer are evaluated by measuring normal-incidence reflection spectra and sensing tests. The high sensitivity (nm/RIU) is observed in silica sphere diameter (1000 > 700 > 400 > 200 nm) and plasmon mode (dipole > Fano resonance (FR) > and high order) while the highest sensitivity is 968 nm/RIU (dipole mode, 1000 nm of silica sphere diameter). 3-D Finite Difference Time Domain (FDTD) simulation shows a sensitivity trend similar to the experimental results.
Keywords:Surface plasmon resonance (SPR);Plasmonics;Nanostructure;Colloidal self-assembly;AuFON;FDTD
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