화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.97, 200-215, May, 2021
DOI10.1016/j.jiec.2021.01.035  Export Citation
MIL-88A (Fe) filler with duplicate corrosion inhibitive/barrier effect for epoxy coatings: Electrochemical, molecular simulation, and cathodic delamination studies
Nariman Alipanah, Hossein Yari†, Mohammad Mahdavian†, Bahram Ramezanzadeh, and Ghasem Bahlakeh1
  • Surface Coating and Corrosion Department, Institute for Color Science and Technology, Tehran, Iran
  • 1Department of Chemical Engineering, Faculty of Engineering, Golestan University, Aliabad Katoul, Iran
E-mail:,
The MIL-88A (Fe) as a MOF based on Fe+3 cations and fumaric acid was fabricated as a corrosion inhibitive filler to achieve a protective coating with duplicate active/passive inhibition properties. The polarization test indicated that the MIL-88A (Fe) saline-based extract had an inhibition effect. The formation of an inhibitive layer was seen in the EIS results for the sample immersed in the MIL-88A (Fe) extract. The slight solubility of MIL-88A (Fe) in the water (122.4 ppm total organic carbon and 2 ppm Fe+3) caused the inhibitive ions' release. The adsorption of release species from MIL-88A (Fe) scaffold on the substrate was confirmed by the theoretical (QM, MC/MD) computations. The EIS and salt spray test results obtained from scratched epoxy coated samples showed the Epoxy-MIL-88A (Fe) coating's active inhibition effect. The pull-off adhesion strength and cathodic delamination resistance were also improved in the presence of MIL-88A (Fe). The adhesion loss of epoxy coatings after 7 days of exposure to the salt spray decreased from 31.4% to 9.4%, respectively. The unscratched samples filled with MIL-88A (Fe) particles showed excellent barrier properties. The breakpoint frequency value declined from 2.4 to 0.8, and the reduction of low-frequency impedance magnitude decreased from 33% to 20%.
Keywords:MOF;MIL-88A;Corrosion inhibition;Molecular simulation;Epoxy coating
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