The aim of this work is to demonstrate the possibility of using electric field forces for the recovery of copper from a fine PVC/Cu granular mixture of low metal content (less than 15%), obtained as "PVC fraction" in the recycling process of electric cable waste from automotive industry, using vibrating table technology. Electrostatic separation of copper granules which are "impurities" in the PVC fraction, increased the overall recovery of copper close to 100%. Granular size classification proved to be a very useful operation in the electrostatic separation process of a particular mixture. The -0.63 mm size class contains the majority of the copper granules and the electrostatic separation allows the recovery of up to 95% copper contained in the granular waste, at purity higher than 99.8%. Copper represents less than 1% in the +0.63 mm size class and can also be recovered with high purity by improving the chopping technology of the cable waste, as well as the separation between the copper and the high conductivity rubber granules.