Gold nanowires (AuNWs) possess strong potential application in micro- and nanoelectronics as well as in plasmonic waveguides because of their low electrical resistance. However, the synthesis of pure solvent-dispersible AuNWs with full control over their length still remains a challenge. All the previously reported methods produce AuNWs with other impurities such as smaller nanorods, platelets, and spherical particles and are limited to a certain length (typically below 10 mu m). This article describes a onestep synthesis of extremely long AuNWs (up to 25 mu m) with great control over their dimensions by using pentahedrally twinned gold nanorods (AuNRs) as seed particles. To induce the AuNW growth, the reduction of Au(I) to Au(0) was carried out on the surface of AuNRs at a very low pH by introducing HC1 into the growth solution. The slow conversion of Au(I) to Au(0) due to the increase in reduction potential at lower pH promoted the preferential deposition of metallic gold on the more reactive tips of AuNRs compared to their sides, resulting in the formation of AuNWs. In analogy to the "living" polymerization reaction, the length of the AuNWs was proportional to the amount of Au(I) added to the growth solution; thus, the desired length of AuNWs was achieved by controlling the supply of Au(I) ions in the reaction mixture. The AuNWs longer than 6 mu m were found to be responsive to microwave radiation. When an aqueous solution of AuNWs was exposed to microwaves, the formation of sharp kinks was observed in several locations of AuNWs without their disintegration into smaller pieces.