화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.29, No.4, 321-326, April, 2021
DOI10.1007/s13233-021-9037-0  Export Citation
Synthesis, CO2 Adsorption and Catalytic Properties of Porphyrin-Pyromellitic Dianhydride Based Porous Polymers
Maher Fathalla1, 2, †
  • 1Department of Chemistry, Faculty of Science, Islamic University of Madinah, Madinah 170, Saudi Arabia
  • 2Department of Chemistry, Faculty of Science, Zagazig University, Zagazig 44519, Egypt
E-mail:
The synthesis, characterization and CO2 uptake tendency of a new porous organic polymer (POP) based on porphyrin-pyromellitic dianhyderide is enclosed. The reported porphyrin POP was achieved by exploiting the condensation reaction between tetraaminophenylporphyrin (TAPP) with benzenetetracarboxylic (pyromellitic) diahhydride in dry dimethylforamide (DMF). The structure of the resulting polymer was confirmed by FT-IR as well as solid state 13C cross-polarization magic angle spinning (CP/MAS) NMR studies. In addition, the post-synthetic metallation of the free-base porphyrin macrocycles of the resulting POP with either Zn or Mn metals afforded the metallo-porphyrin POP analogues in excellent yields. The morphology of the reported porphyrin POPs were investigated by scanning electron microscopy (SEM) which demonstrated the porosity of the resulting POPs. Furthermore, CO2 adsorption capabilities of the synthesized POPs were evaluated and Brunauer-Emmett Teller (BET) surface area was found to be 542, 597 and 828 m2/g for free-base, Zn- and MnIII-POP, respectively. Finally, MnIII-POP was found to be an effective catalyst for the selective epoxidation of styrene to the corresponding epoxide.
Keywords:porous polymers;porphyrin;catalysis;CO2 uptake;epoxides
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