Unraveling the morphology of the sensing material is of paramount in realizing the better sensitivity. For this purpose, the Bi2Ti2O7:Yb3+/Er3+ nanofibers (0:1, 4:1, 8:1, 15:1, 20:1) and nanoparticles were synthesized via an electrospinning and sol-gel route, respectively. Subsequently, the temperature sensing properties based on the fluorescence intensity ration were studied within Bi2Ti2O7:Yb3+/Er3+ nanofibers and particles in the range of 298-538 K. The maximum relative sensitivity value was 1.53% at 298 K for Bi2Ti2O7:Yb3+/Er3+ (4:1) nanofibers. As was expected, Bi2Ti2O7:Yb3+/Er3+ nanofibers demonstrated an enhanced temperature sensitivity than that of the individual nanoparticles, exhibiting the champion values among all the reported Yb-Er pairs. To exploit the potential for practical application, the Bi2Ti2O7:Yb3+/Er3+ nanofibers were utilized to measure the surface temperature of a heating object. An improved surface temperature resolution was realized compare with the infrared thermal camera. All the presented results confirmed that the novel upconversion Bi2Ti2O7:Yb3+/Er3+ nanofibers could be an outstanding candidate for temperature sensors. Our work has proven to be a reliable alternative for exploring contactless temperature sensing at a higher resolution.