As well-known, hydrated vanadium pentoxide (V2O5 center dot nH(2)O) has a larger layer spacing than orthogonal V2O5, which could offer more active sites to accommodate lithium ions, ensuring a high specific capacity. However, the exploration of V2O5 center dot nH(2)O cathode is limited by its inherently low conductivity and slow electrochemical kinetics, leading to a significant decrease in capability. Herein, we prepared V2O5 center dot nH(2)O/reduced graphene oxide (rGO) composite with low rGO content (8 wt%) via a simple yet effective dual electrostatic assembly strategy. When used as the cathode material for lithium-ion batteries (LIBs), V2O5 center dot nH(2)O/rGO manifests a high reversible capacity of 268 mAh g(-1) at 100 mA g(-1) and especially an excellent rate capability (196 mAh g(-1) at 1000 mA g(-1) and 129 mA h g(-1) at 2000 mA g(-1)), surpassing those of the V2O5/carbon composites reported in the literatures. Notably, the remarkable performance should be referable to the synergetic effects between one-dimensional V2O5 center dot nH(2)O nanobelts and two-dimensional rGO nanosheets, which provide a short transport pathway and enhanced electrical conductivity. This strategy opens a new opportunity for designing high-performance cathode material with excellent rate performance for advanced LIBs. (C) 2020 Elsevier Inc. All rights reserved.