화학공학소재연구정보센터
Journal of Colloid and Interface Science, Vol.587, 622-632, 2021
Titanium niobate (Ti2Nb10O29) anchored on nitrogen-doped carbon foams as flexible and self-supported anode for high-performance lithium ion batteries
Assembling active materials on flexible conductive matrixes for fabricating high-rate, self-supported and durable anodes is essential for the development of high-power flexible lithium-ion batteries. In this study, we report an efficient combinational strategy for producing hybrid composites (TNO@MCF) of Ti2Nb10O29 (TNO) anchored on melamine carbon foam (MCF) via a hydrothermal method. The N-doped MCF not only showed good electronic conductivity and flexibility, but also improved the ion transport performance of the composites. The TNO@MCF electrode exhibited remarkably high rate capacities (327 mA h g(-1)at 1 C, and 205 mA h g(-1) at 40 C) and excellent cycling stability with a high capacity retention of 81.4% after 1000 cycles at 10 C. After 100 compression-rebound cycles, the TNO@MCF electrode showed a reversible capacity of 315 mA h g(-1) at 1 C and exhibited a capacity retention of 72.3% for 1000 cycles at 10 C. This compressible structure design could provide guidelines for manufacture of other flexible electrodes for energy storage devices. (c) 2020 Elsevier Inc. All rights reserved.