A unique three-dimension (3D) porous network structure where N-doped reduced graphene oxide aerogels (N-rGA) are decorated by raspberry-like CoFe2O4 (CFO) clusters. Super-broad effective microwave absorption bandwidth (7.28 GHz) of the CFO/N-rGA composite is obtained at 2.53 mm by changing N contents. Here, the dipolar relaxation loss and conduction loss are highly sensitive to the presence of pyridinic, pyrrolic and graphitic N in the CFO/N-rGA composites. A minimum reflection loss of the CFO/N-rGA composites reaches up to -55.43 dB at 15.36 GHz with a matching thickness (2.3 mm) and low filler loading (10 wt%). Its effective absorption bandwidth completely covers X-band from 7.76 to 12.72 GHz at 3.3 mm. The high-efficiency microwave absorption of the composites mainly results from the enhanced polarization relaxation, the specific design of conductive network and the superior impedance matching. This study offers a promising technical route to explore new N-doped magnetic/dielectric composites as ideal microwave absorbers. (C) 2021 Elsevier Inc. All rights reserved.