Journal of Chemical and Engineering Data, Vol.66, No.1, 848-851, 2021
Comment on "Isobaric Vapor plus Liquid Equilibrium Measurements and Calculations for Using Nontraditional Models for the Association Systems of Ethyl Acetate+2-Ethylhexanoic Acid and Propyl Acetate+2-Ethylhexanoic Acid at Atmospheric Pressure"
Shen et al. have recently reported isobaric VLE data for two binary systems. The purpose of this communication is to prove that their data are actually thermodynamically inconsistent and erroneously modeled and to show in detail the various mistakes made by the authors.