Extraction residue (ER) is, in this study, considered as an insoluble portion derived from a novel extraction process with direct coal liquefaction residue, which is the byproduct from 1000 kton/y direct coal liquefaction and oil production process in Ordos, China. ER mostly consists of unreacted coal and minerals, spent catalyst, and solvent. It is considered as a hazardous waste in China. Gasification is a promising way to employ ER, as the carbon resource contained in it could be adequately utilized, so strongly reducing the environmental impact of this material. In this paper, a kinetic study is carried out concerning CO2 gasification (in thermobalance) of ER char, coal char, and their blends. The results show that, at temperatures ranging from 1123 to 1323 K, the reactivity of ER char is much larger than that of coal char, and the reactivity of ER/coal char blends increases when the ER fraction increases, consistently resulting in between the reactivities shown by ER char and coal char alone. The partial pressure of CO2 promotes the reactivity of all samples. BET surface area resulted three times larger for ER char vs coal char, while pore surface area and pore volume were four times larger. Moreover, the relevant parameters of the random pore model for CO2 gasification of ER char, coal char, and their blend #2 (with 20% ER) were obtained; the activation energy resulted 210.6, 240.5, and 232.8 kJ/mol, and the reaction order 0.30, 0.45, and 0.40, respectively.