Na3Bi(IO3)(6): An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition

Song HM; Jiang DQ; Wang NZ; Xing WH; Guo RX; Lin ZS; Yao JY; Wang YG; Tu H; Zhang GC

Inorganic Chemistry, Vol.60, No.5, 2893-2898, 2021

DOI10.1021/acs.inorgchem.0c03697 Export Citation

Na3Bi(IO3)(6): An Alkali-Metal Bismuth Iodate with Intriguing One-Dimensional [BiI6O18] Chains and Pressure-Induced Structural Transition

Song HM, Jiang DQ, Wang NZ, Xing WH, Guo RX, Lin ZS, Yao JY, Wang YG, Tu H, Zhang GC

An alkali-metal bismuth iodate, Na3Bi(IO3)(6), was successfully obtained by the hydrothermal method for the first time and contains intriguing one-dimensional [BiI6O18] chains. High-pressure Raman spectra were carried out to investigate the structural transition of Na3Bi(IO3)(6). Electronic states and anisotropic optical responses were also investigated by theoretical calculations.