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Chinese Journal of Chemical Engineering, Vol.28, No.11, 2707-2722, 2020
A review on single bubble gas-liquid mass transfer
It is common to empirically correlate volumetric mass transfer coefficient k(L)a for predicting gas-liquid mass transfer in industrial applications, and the investigation of single bubble mass transfer is crucial for a detailed understanding of mass transfer mechanism. In this work, experiments, models and simulations based on the experimental results were highlighted to elucidate the mass transfer between single bubbles and ambient liquid. The experimental setups, measurement methods, the mass transfer of single bubbles in the Newtonian and the non-Newtonian liquid, models derived from the concept of eddy diffusion, the extension of Whitman's, Higbie's and Danckwerts' models, or dimensionless numbers, and simulation methods on turbulence, gas-liquid partition methods and mass transfer source term determination are introduced and commented on. Although people have a great knowledge on mass transfer between single bubbles and ambient liquid in single conditions, it is still insufficient when facing complex liquid conditions or some phenomena such as turbulence, contamination or non-Newtonian behavior. Additional studies on single bubbles are required for experiments and models in various liquid conditions in future. (C) 2020 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved.
Keywords:Gas-liguid mass transfer;Single bubbles;Mass transfer models;Simulation;Surfactant;Non-Newtonian fluid