화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.95, 224-234, March, 2021
DOI10.1016/j.jiec.2020.12.023  Export Citation
Facile synthesis of graphite oxide/MIL-101(Cr) hybrid composites for enhanced adsorption performance towards industrial toxic dyes
The Ky Vo†, Tra Phuong Trinh, Van Cuong Nguyen, and Jinsoo Kim1, †
  • Department of Chemical Engineering, Industrial University of Ho Chi Minh City, 12 Nguyen Van Bao, Go Vap, Ho Chi Minh City, Vietnam, Korea
  • 1Department of Chemical Engineering (Integrated Engineering), Kyung Hee University, 1732 Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 17104 Korea
E-mail:,
Graphite oxide (GrO), as a superb platform with highly dense arrays of atoms and abundant functionalities, can increase dispersive forces within metal.organic frameworks (MOFs), which provides a feasible strategy to control physicochemical properties of MOFs. In this study, a series of hybrid GrO/ MIL-101(Cr) (GrO@MCr) nanocomposites were readily prepared via hydrothermal synthesis. The prepared composites were applied to remove methyl orange (MO) and reactive blue 198 (RB198) as organic pollutants from an aqueous solution. The surface area of GrO@MCr composite increased from 2980 to 3540 m2 g 1 with increasing GrO loading amount from 0 to 6.0 wt.%. The highest adsorption capacities of MO (235 mg g-1) and RB198 (175 mg g-1) were obtained at 25 °C and pH = 5.5 using 6 wt.% GrO loaded GrO@MCr composite; these values were 2.3 and 1.97 times higher than that of pristine MIL-101(Cr). The reusability and stability analyses showed that the sorption capacities of MO and RB198 onto the fabricated GrO@MCr decreased to 89% and 86%, respectively, after five adsorption.desorption cycles. Moreover, the adsorption kinetics and adsorption isotherms were studied in detail to investigate the adsorption mechanism.
Keywords:GrO/MIL-101(Cr);Graphite oxide;MIL-101(Cr);Dye adsorption;Methyl orange. Reactive blue 198
  1. Natarajan S, Bajaj HC, Tayade RJ, J. Environ. Sci., 65, 201 (2018)
  2. Ramesha GK, Kumara AV, Muralidhara HB, Sampath S, J. Colloid Interface Sci., 361(1), 270 (2011)
  3. Alkan M, Celikcapa S, Demirbas O, Dogan M, Dyes Pigment., 65, 251 (2005)
  4. Eren E, Afsin B, Dyes Pigment., 73, 162 (2007)
  5. Vo TK, Park HK, Nam CW, Kim SD, Kim JS, J. Ind. Eng. Chem., 60, 485 (2018)
  6. Saravanan R, Khan MM, Gupta VK, Mosquera E, Gracia F, Narayanan V, Stephen A, J. Colloid Interface Sci., 452, 126 (2015)
  7. Ali I, Burakova I, Galunin E, Burakov A, Mkrtchyan E, Melezhik A, Kurnosov D, Tkachev A, Grachev V, ACS Omega, 4, 19293 (2019)
  8. Ali I, Alharbi OML, Alothman ZA, Alwarthan A, Colloids Surf. B: Biointerfaces, 171, 606 (2018)
  9. Gupta VK, Saleh TA, Environ. Sci. Pollut. Res., 20, 2828 (2013)
  10. Rajendran S, Khan MM, Gracia F, Qin J, Gupta VK, Arumainathan S, Sci. Rep., 6, 31641 (2016)
  11. Vo TK, Kim JS, Korean J. Chem. Eng., 37(3), 571 (2020)
  12. Robati D, Mirza B, Rajabi M, Moradi O, Tyagi I, Agarwal S, Gupta VK, Chem. Eng. J., 284, 687 (2016)
  13. Saleh TA, Ali I, J. Environ. Chem. Eng., 6, 5361 (2018)
  14. Dil EA, Ghaedi M, Ghaedi AM, Asfaram A, Goudarzi A, Hajati S, Soylak M, Agarwal S, Gupta VK, J. Ind. Eng. Chem., 34, 186 (2016)
  15. Suhas, Gupta VK, Carrott PJM, Singh R, Chaudhary M, Kushwaha S, Bioresour. Technol., 216, 1066 (2016)
  16. Saravanan R, Khan MM, Gupta VK, Mosquera E, Gracia F, Narayanan V, Stephen A, RSC Adv., 5, 34645 (2015)
  17. Xiong W, Zeng G, Yang Z, Zhou Y, Zhang C, Cheng M, Liu Y, Hu L, Wan J, Zhou C, Xu R, Li X, Sci. Total Environ., 627, 235 (2018)
  18. Qiu JH, Feng Y, Zhang XF, Jia MM, Yao JF, J. Colloid Interface Sci., 499, 151 (2017)
  19. Gong R, Sun Y, Chen J, Liu H, Yang C, Dyes Pigment., 67, 175 (2005)
  20. Saleh TA, Tuzen M, Sarı A, J. Environ. Manage., 211, 323 (2018)
  21. Ali I, Al-Hammadi SA, Saleh TA, J. Mol. Liq., 269, 564 (2018)
  22. Saleh TA, Trends Environ. Anal. Chem., 25, e00080 (2020)
  23. Mittal A, Mittal J, Malviya A, Gupta VK, J. Colloid Interface Sci., 344(2), 497 (2010)
  24. Nekouei F, Nekouei S, Tyagi I, Gupta VK, J. Mol. Liq., 201, 124 (2015)
  25. Burakov AE, Galunin EV, Burakova IV, Kucherova AE, Agarwal S, Tkachev AG, Gupta VK, Ecotoxicol. Environ. Saf., 148, 702 (2018)
  26. Adebajo MO, Frost RL, Kloprogge JT, Carmody O, Kokot S, J. Porous. Mat., 10, 159 (2003)
  27. Gupta VK, Suhas J, Environ. Manage., 90, 2313 (2009)
  28. Ahmaruzzaman M, Gupta VK, Ind. Eng. Chem. Res., 50(24), 13589 (2011)
  29. Sohrabnezhad S, Pourahmad A, Desalination, 256(1-3), 84 (2010)
  30. Kasmi T, Soualah A, Mignard S, Batonneau-Gener I, J. Environ. Health Sci. Eng., 16, 239 (2018)
  31. Wang SB, Sun HQ, Ang HM, Tade MO, Chem. Eng. J., 226, 336 (2013)
  32. Liu H, Wu T, Wu Z, Zhang Y, Xuan K, Zhang J, Tan S, Water Sci. Technol., 70, 851 (2014)
  33. Zhang N, Qiu H, Si Y, Wang W, Gao J, Carbon, 49, 827 (2011)
  34. Sui Z, Meng Q, Zhang X, Ma R, Cao B, J. Mater. Chem., 22, 8767 (2012)
  35. Hu X, Mu L, Wen J, Zhou Q, J. Hazard. Mater., 213-214, 387 (2012)
  36. Lei X, Li X, Ruan Z, Zhang T, Pan F, Li Q, Xia D, Fu J, J. Mol. Liq., 266, 122 (2018)
  37. Al Nafiey A, Addad A, Sieber B, Chastanet G, Barras A, Szunerits S, Boukherroub R, Chem. Eng. J., 322, 375 (2017)
  38. Song ZJ, Ran W, Wei FY, Water Sci. Technol., 75, 397 (2016)
  39. Vo TK, Kim JH, Kwon HT, Kim JS, J. Ind. Eng. Chem., 80, 345 (2019)
  40. Vo TK, Le VN, Yoo KS, Song M, Kim D, Kim J, Cryst. Growth Des., 19, 4949 (2019)
  41. Vo TK, Le VN, Nguyen VC, Song M, Kim DK, Yoo KS, Park BJ, Kim JS, J. Ind. Eng. Chem., 86, 178 (2020)
  42. Zhao ZX, Li XM, Li Z, Chem. Eng. J., 173(1), 150 (2011)
  43. Wang T, Zhao P, Lu N, Chen HC, Zhang CL, Hou XH, Chem. Eng. J., 295, 403 (2016)
  44. Karmakar S, Roy D, Janiak C, De S, Sep. Purif. Technol., 215, 259 (2019)
  45. Hou P, Xing G, Han D, Zhao Y, Zhang G, Wang H, Zhao C, Yu C, J. Porous. Mat., 26, 1607 (2019)
  46. Jabbari V, Veleta JM, Zarei-Chaleshtori M, Gardea-Torresdey J, Villagran D, Chem. Eng. J., 304, 774 (2016)
  47. Eddaoudi M, Kim J, Rosi N, Vodak D, Wachter J, O’Keeffe M, Yaghi OM, Science, 295, 469 (2002)
  48. Fang Z, Bueken B, De Vos DE, Fischer RA, Angew. Chem.-Int. Edit., 54, 7234 (2015)
  49. Yan Q, Lin Y, Kong C, Chen L, Chem. Commun., 49, 6873 (2013)
  50. Wu L, Xue M, Qiu SL, Chaplais G, Simon-Masseron A, Patartin J, Microporous Mesoporous Mater., 157, 75 (2012)
  51. Zhou ZY, Mei L, Ma C, Xu F, Xiao J, Xia QB, Li Z, Chem. Eng. Sci., 147, 109 (2016)
  52. Sun XJ, Xia QB, Zhao ZX, Li YW, Li Z, Chem. Eng. J., 239, 226 (2014)
  53. Ahmed I, Jhung SH, Mater. Today, 17, 136 (2014)
  54. Xue Y, Zheng S, Xue H, Pang H, J. Mater. Chem. A., 7, 7301 (2019)
  55. Tari NE, Tadjarodi A, Tamnanloo J, Fatemi S, Microporous Mesoporous Mater., 231, 154 (2016)
  56. Petit C, Bandosz TJ, Adv. Funct. Mater., 21(11), 2108 (2011)
  57. Petit C, Mendoza B, Bandosz TJ, ChemphysChem, 11, 3678 (2010)
  58. Huang ZH, Liu G, Kang F, ACS Appl. Mater. Interfaces, 4, 4942 (2012)
  59. Xiang Z, Peng X, Cheng X, Li X, Cao D, J. Phys. Chem. C, 115, 19864 (2011)
  60. Wu SC, Yu LL, Xiao FF, You X, Yang C, Cheng JH, J. Alloy. Compd., 724, 625 (2017)
  61. Sun Y, Chen M, Liu H, Zhu Y, Wang D, Yan M, Appl. Surf. Sci., 525, 146614 (2020)
  62. Wen M, Mori K, Kamegawa T, Yamashita H, Chem. Commun., 50, 11645 (2014)
  63. Leng K, Sun Y, Li X, Sun S, Xu W, Cryst. Growth Des., 16, 1168 (2016)
  64. Fu GZC, Zhang H, Li S, Int. J. Electrochem. Sci., 8, 6269 (2013)
  65. Wang J, Wang Y, Zhang Y, Uliana A, Zhu J, Liu J, Van der Bruggen B, ACS Appl. Mater. Interfaces, 8, 25508 (2016)
  66. Saleh TA, J. Clean Prod., 172, 2123 (2018)
  67. Priya B, Gupta VK, Pathania D, Singha AS, Carbohydr. Polym., 109, 171 (2014)
  68. Liu Q, Ning L, Zheng S, Tao M, Shi Y, He Y, Sci. Rep., 3, 2916 (2013)
  69. Xie Q, Li Y, Lv Z, Zhou H, Yang X, Chen J, Guo H, Sci. Rep., 7, 3316 (2017)
  70. Saleh TA, Desalin. Water. Treat., 57, 10730 (2016)
  71. Vo TK, Bae YS, Chang BJ, Moon SY, Kim JH, Kim J, Microporous Mesoporous Mater., 274, 17 (2019)
  72. Chen Y, Ding K, Yang L, Xie B, Song F, Wan J, Wang G, Han M, Appl. Phys. Lett., 92, 173112 (2008)
  73. Zhang Z, Li X, Liu B, Zhao Q, Chen G, RSC Adv., 6, 4289 (2016)
  74. Huang X, Hu N, Gao R, Yu Y, Wang Y, Yang Z, Kong ESW, Wei H, Zhang Y, J. Mater. Chem., 22, 22488 (2012)
  75. Saleh TA, J. Water Supply Res. T., 64, 892 (2015)
  76. Zhao Y, Seredych M, Zhong Q, Bandosz TJ, ACS Appl. Mater. Interfaces, 5, 4951 (2013)
  77. Petit C, Bandosz TJ, Adv. Mater., 21(46), 4753 (2009)
  78. Haque E, Lee JE, Jang IT, Hwang YK, Chang JS, Jegal J, Jhung SH, J. Hazard. Mater., 181(1-3), 535 (2010)
  79. Wu QY, Liang HQ, Li M, Liu BT, Xu ZK, Chinese J. Polym. Sci., 34, 23 (2016)