Surface and foam property of perfluoroalkyl polyoxyethylene ether phosphate salt in aqueous-ethanol system

Bo Ning; Yan Wang; Mi Zhang; Yanyun Bai; Xiumei Tai; Wanxu Wang; Guoyong Wang

Journal of Industrial and Engineering Chemistry, Vol.94, 217-224, February, 2021

DOI10.1016/j.jiec.2020.10.039 Export Citation

Surface and foam property of perfluoroalkyl polyoxyethylene ether phosphate salt in aqueous-ethanol system

Bo Ning, Yan Wang¹, Mi Zhang, Yanyun Bai, Xiumei Tai, Wanxu Wang, and Guoyong Wang^†

China Research Institute of Daily Chemical Industry, Taiyuan 030001, PR China
¹School of Chemical & Biological Engineering, Taiyuan University of Science and Technology, Taiyuan 030024, PR China

E-mail:

Foam is used in many fields with excellent performance. Moreover, disinfectants with ethanol as the main ingredient have increasingly been used in people's lives. However, the foam research of an ethanol-water mixed system is still in the initial stage. In this work, a perfluoroalkyl polyoxyethylene ether phosphate salt surfactant (FEP-Na) was synthesized through a new molecular design. The surfactant has good interfacial adsorption behavior in 50% ethanol-water mixing system, and the approximately spherical aggregates are observed in the volume phase of the solution. Moreover, FEP-Na showed good foaming property in 50% ethanol-water mixed solution. Interestingly, high concentration solutions with high surface activity have lower foam stability. And under the microscope, we see that the bubble burst is dominated by the phenomenon of coalescence. In this regard, we explain the mechanism of foam stability by electrostatic double layer theory and interfacial dilation rheology. It provides a new choice for the synthesis of foaming agent in the ethanol-water mixed system at a concentration of 50%.

Keywords:Fluorocarbon surfactants;Foam;Aqueous-Ethanol mixed System;Electrostatic double-layer film

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[2] Tian J, Chen Z, Yang Y, Liang H, Nan J, Li G, Water Res., 44, 59 (2010)

[3] Gonzalez-Rivera J, Iglio R, Barillaro G, Duce C, Tine MR, Polymers-Basel, 10 (2018)

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[6] Yu X, Jiang N, Miao X, Zong R, Sheng Y, Li C, Lu S, Colloids Surf. A: Physicochem. Eng. Asp., 591 (2020)

[7] Hinnant KM, Giles SL, Smith EP, Snow AW, Ananth R, Fire Technol, 56, 1413 (2020)

[8] Zhang L, Mikhailovskaya A, Yazhgur P, Muller F, Cousin F, Langevin D, Wang N, Salonen A, Angew. Chem.-Int. Edit., 54, 9533 (2015)

[9] Dombrowski J, Gschwendtner M, Kulozik U, Colloids Surf. A: Physicochem. Eng. Asp., 516, 286 (2017)

[10] Li G, Zheng L, Xiao J, J. Fluor. Chem., 130, 674 (2009)

[11] Perek B, Lipski A, Stefaniak S, Jemielity M, J. Thorac. Cardiovasc. Surg., 10, 177 (2013)

[12] de Carvalho LD, Silva LRE, Brum Paiva CB, Viana AR, Amaro WL, medical-forensic implications, 22nd Congress of the International-Academy-of-Legal-Medicine (IALM), 155 (2013).

[13] Rotter M, et al., Zentralblatt Fur Bakteriologie Mikrobiologie Und Hygiene Serie B-Umwelthygiene Krankenhaushygiene Arbeitshygiene Praventive Medizin, 164, 428 (1977).

[14] Karakashev SI, Manev ED, Nguyen AV, Colloids Surf. A: Physicochem. Eng. Asp., 319, 34 (2008)

[15] Ridings C, Andersson GG, ChemphysChem, 16, 733 (2015)

[16] Shen J, Bai Y, Tai X, Wang W, Wang G, ACS Sustain Chem Eng, 6, 6183 (2018)

[17] Krafft MP, Riess JG, Chemosphere, 129, 4 (2015)

[18] Verdia P, Gunaratne HQN, Goh TY, Jacquemin J, Blesic M, Green Chem., 18, 1234 (2016)

[19] Zhang B, He Y, Huang Y, Hong D, Yao Y, Wang L, Sun W, Yang B, Huang X, Song S, Bai X, Guo Y, Zhang T, Sun H, Environ Pollut., 263 (2020)

[20] Zhang B, He Y, Huang Y, Hong D, Yao Y, Wang L, Sun W, Yang B, Huang X, Song S, Bai X, Guo Y, Zhang T, Sun H, Environ Pollut, 263 (2020)

[21] Kim M, Kim T, Kim T, Joo S, Zho K, Sep Purif Technol, 247 (2020)

[22] Liu S, Yang R, Yin N, Faiola F, Chemosphere, 254 (2020)

[23] Miyashita M, Akamatsu M, Sakai K, Sakai H, Chem Lett, 49, 453 (2020)

[24] Sun YQ, Gao T, Metall Mater Trans A, 33, 3285 (2002)

[25] Chattopadhyay P, Karthick RA, Macromol Symp, 376, 160018 (2017)

[26] Krafft MP, Riess JG, Chemosphere, 129, 4 (2015)

[27] Eriksson JC, Toshev BV, Coll Surf, 5, 241 (1982)

[28] Bergeron V, J. Phys. Condens. Matter, 11, R215 (1999)

[29] Hu H, Weinberger CR, Sun Y, Nano Lett., 14, 7131 (2014)

[30] Chen S, Zhou Y, Wang G, Li W, Zhu Y, Zhang J, J. Dispersion Sci. Technol., 37, 479 (2016)