화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.38, No.2, 306-315, February, 2021
Bio-oil production from fast pyrolysis of furniture processing resid
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The pyrolysis characteristic of furniture processing residue (FPR), which was analyzed by thermogravimetric analysis (TGA) under nitrogen atmosphere, mainly decomposed between 230 °C and 500 °C. The FPR was submitted to fast pyrolysis in a bubbling fluidized-bed reactor (BFR) for converting into bio-oil, bio-char. The product distribution and characteristics of bio-oil depend on the operating conditions (temperature, fluidizing flow rate, particle size of sample). The bio-oil yield showed the highest value (50.68 wt%) at the pyrolysis temperature of 450 °C with a biomass particle size of 1.0mm and a fluidization velocity of 2.0×Umf. The bio-oil had high selectivity for dioctyl phthalate, levoglucosan, and phenolic derivatives. The carbon number proportions in bio-oils of FPR were 32.74wt% for C5- C11 fraction, 47.60 wt% for C12-C18 fraction and 19.38 wt% of C25-C38 fraction, respectively. The gas product included CO, CO2, H2, and hydrocarbons (C1-C4), and the selectivity of CO2 was the highest. The high heating value (HHV) of gas products was between 4.60 and 12.90 MJ/m3. The bio-char shows high HHV (23.87 MJ/kg) and high C content (62.47wt%) that can be applied as a solid fuel.
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