화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.28, No.12, 1134-1141, November, 2020
DOI10.1007/s13233-020-8148-3  Export Citation
Preparation of Responsive Zwitterionic Diblock Copolymers Containing Phosphate and Phosphonate Groups
Yasemin Samav1, 2, Bernice Akpinar2, Gökhan Kocak3, and Vural Bütün2, †
  • 1Department of Chemistry and Chemical Process Technologies, Vocational School of Higher Education, Bilecik Seyh Edebali University, 11210, Bilecik, Turkey
  • 2Department of Chemistry, Facullty of Science and Letters, Eskisehir Osmangazi University, 26040, Eskisehir, Turkey
  • 3Department of Chemistry and Chemical Process Technologies, Vocational School of Higher Education, Adiyaman University, 02040, Adiyaman, Turkey
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In this study, novel zwitterionic diblock copolymers, namely poly(2-(N-morpholino)ethyl methacrylate))-block-poly(2-(methacryloyloxy)ethyl phosphate) (PMEMA-b-PMOEP) and poly(2-(N-morpholino)ethyl methacrylate))-block-poly ((methacryloyloxy)methyl phosphonic acid) (PMEMA-b-PMOMP), were synthesized via reversible addition-fragmentation chain transfer controlled radical polymerization. Solution properties of these phosphorus-based diblock copolymers were investigated using dynamic light scattering, transmission electron microscopy and proton nuclear magnetic resonance spectroscopy. Since the PMEMA block has both salt- and thermo-responsive properties, PMEMA-b-PMOEP and PMEMA-b-PMOMP diblock copolymers formed core-shell micelles in basic aqueous media as the PMEMA block formed insoluble micelle core with the addition of Na2SO4 or an increase in temperature in basic solution. Additionally, PMEMA-b-PMOMP diblock copolymers interacted strongly with calcium cations and yielded reverse micellar structures via complexation of phosphate with metal cation in aqueous media.
Keywords:pH-responsive polymer;temperature-responsive polymer;zwitterionic polymers;phosphorus-based polymers;micelles;self-assembly;nanoparticles;diblock copolymer
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