화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.37, No.12, 2192-2201, December, 2020
DOI10.1007/s11814-020-0629-8  Export Citation
Adsorption of Direct Red 23 dye from aqueous solution by means of modified montmorillonite nanoclay as a superadsorbent: Mechanism, kinetic and isotherm studies
Seyedeh Mahtab Pormazar1, 2, and Arash Dalvand1, †
  • 1Environmental Science and Technology Research Center, Department of Environmental Health Engineering, School of Public Health, Shahid Sadoughi University of Medical Sciences, Yazd, Iran
  • 2Student Research Committee, Shahid Sadoughi University of Medical Sciences, Yazd, Iran
E-mail:
A novel adsorbent of modified nanoclay was synthesized by covering of alum on the montmorillonite nanoclay (Al/nanoclay). Al/nanoclay was applied as an efficient superadsorbent to remove Direct Red 23 (DR23) from colored wastewater. The adsorbent was characterized by Fourier transform infrared spectroscopy, energy-dispersive Xray spectroscopy, and zeta potential analysis. The effects of various operating parameters, such as contact time, initial dye concentration, adsorbent dose, pH and ionic strength on the performance of adsorption, have been studied. The adsorption experiments showed that pH has an obvious effect on the adsorption efficiency and the highest percentage of DR23 dye removal was observed at pH 2. Zeta potential measurement confirmed that the adsorption mechanism is ascribed to electrostatic interaction between sulfonic groups of the anionic dye and the positive surface charge of the adsorbent. The pseudo-second-order kinetic model and the Langmuir isotherm were found to best describe the DR23 adsorption and the maximum monolayer adsorption capacity at the conditions of pH 2 and the adsorbent dose of 0.05 g/L was 2,500mg/g. The findings recommend that Al/nanoclay can be successfully used for DR23 dye removal from the colored wastewater.
Keywords:Adsorption;Direct Red 23 Dye;Mechanism;Modified Montmorillonite Nanoclay
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