화학공학소재연구정보센터
Korean Journal of Materials Research, Vol.30, No.10, 550-557, October, 2020
과립분말 유동성 변화가 부조세라믹타일의 소결거동에 미치는 영향
Influence of Flowability of Ceramic Tile Granule Powders on Sintering Behavior of Relief Ceramic Tile
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Used in the ceramic tile market as a representative building material, relief ceramic tile is showing increased demand recently. Since ceramic tiles are manufactured through a sintering process at over 1,000 °C after uniaxial compression molding by loading granule powders into a mold, it is very important to secure the flowability of granular powders in a mold having a relief pattern. In this study, kaolin, silica, and feldspar are used as starting materials to prepare granule powders by a spray dryer process; the surface of the granule powders is subject to hydrophobic treatment with various concentrations of stearic acid. The effect on the flowability of the granular powder according to the change of stearic acid concentration is confirmed by measuring the angle of repose, tap density, and compressibility, and the occurrence of cracks in the green body produced in the mold with the relief pattern is observed. Then, the green body is sintered by a fast firing process, and the water absorption, flexural strength, and durability are evaluated. The surface treatment of the granule powders with stearic acid improves the flowability of the granule powders, leading to a dense microstructure of the sintered body. Finally, the hydrophobic treatment of the granule powders makes it possible to manufacture relief ceramic tiles having a flexural strength of 292 N/cm, a water absorption of 0.91 %, and excellent mechanical durability
  1. Dondi M, Raimondo M, Zanelli C, Appl. Clay Sci., 96, 91 (2014)
  2. Kim JH, Noh HG, Kim US, Cho WS, Choi JH, Lee YO, J. Korean Ceram. Soc., 50, 1 (2013)
  3. Kim JH, Kim US, Han KS, Hwang KT, Korean J. Mater. Res., 29(7), 425 (2019)
  4. Shu Z, Garcia-Ten J, Monfort E, Amoros JL, Wang YX, Ceram. Int., 38, 517 (2012)
  5. Byeon SC, Je HJ, Hong KS, J. Korean Ceram. Soc., 32, 549 (1995)
  6. Shu Z, Zhou J, Wang YX, J. Clean Prod., 18, 1045 (2010)
  7. Bertranda G, Filiatreb C, Mahdjouba H, Foissyb A, Coddeta C, J. European Ceram. Soc., 23, 263 (2003)
  8. Pusapati RT, Rao TV, Indian J. Res. Pharm. Biotechnol., 2, 1360 (2014)
  9. Hemati A, Cherif R, Saleh K, Pont V, Powder Technol., 130(1-3), 18 (2003)
  10. Choi JH, Kang ET, Lee JW, Kim US, Cho WS, J. Ceram. Process. Res., 19, 43 (2018)
  11. Jeong SB, Hyun JY, Chae YB, J. Korean Soc. Miner. Energy Resour. Eng., 41, 490 (2004)
  12. Nampi PP, Kume S, Hotta Y, Watari K, Itoh M, Toda H, Matsutani A, Ceram. Int., 37, 3445 (2011)
  13. Gualtieri ML, Romagnoli M, Gualtieri AF, J. European Ceram. Soc., 31, 673 (2011)
  14. Soldati R, Zanelli C, Guarini G, Fazio S, Bignozzi MC, Dondi M, J. European Ceram. Soc., 38, 4118 (2018)
  15. Henkes VE, Onoda GY, Carty W, Science of Whitewares, p.112, Wiley (1996).
  16. Yoo BR, Jung DE, Polym. Sci. Technol., 20, 124 (2009).
  17. Carr RL, Chem. Eng., 72, 163 (1965)
  18. Shu Z, Garcia-Ten J, Monfort E, Amoros JL, Wang YX, Ceram. Int., 38, 1479 (2012)