화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Korean Journal of Chemical Engineering, Vol.37, No.11, 1963-1974, November, 2020
DOI10.1007/s11814-020-0599-x  Export Citation
Fabrication of antifouling mixed matrix NF membranes by embedding sodium citrate surfactant modified-iron oxide nanoparticles
Abdolreza Moghadassi†, Sara Moradi, and Samaneh Bandehali
  • Department of Chemical Engineering, Faculty of Engineering, Arak University, Arak 38156-8-8349, Iran
E-mail:
PES-based nanofiltration membranes were prepared by phase inversion method. Fe3O4 nanoparticles with a constant concentration and sodium citrate in different concentration were incorporated into the PES. The membranes were characterized by Fourier transform infrared spectroscopy (FTIR), Field emission scanning electron microscopy (FESEM), EDX dot mapping and Atomic force microscope (AFM) analysis. Physico-chemical, antifouling properties, and separation performance of the fabricated membranes were investigated by the contact angle, pure water flux (PWF), Na2SO4 rejection and flux recovery ratio (FRR%). The membrane porosity and mean pore size enhanced for the modified membranes compared the bare membrane. The PWF sharply improved from 16 L/m2h in the bare membrane to 47 L/m2h at 0.5 wt% Fe3O4 and 0.3 wt% sodium citrate (M5). The highest salt rejection obtained was 68%, while it was 61% for the bare membrane. Better dispersion of Fe3O4 nanoparticles into the casting solution with outstanding antifouling properties was observed.
Keywords:Nanofiltration Membrane;Iron Oxide Nanoparticle;Sodium Citrate;Antifouling Properties
  1. Hu RR, Zhang RJ, He YJ, Zhao GK, Zhu HW, J. Membr. Sci., 564, 813 (2018)
  2. Madaeni SS, Arast N, Rahimpour F, Arast Y, Desalination, 280(1-3), 305 (2011)
  3. Ji YL, Qian WJ, Yu YW, An QF, Liu LF, Zhou Y, Gao CJ, Chin. J. Chem. Eng., 25(11), 1639 (2017)
  4. Mertens M, Van Dyck T, Van Goethem C, Gebreyohannes AY, Vankelecom IFJ, J. Membr. Sci., 557, 24 (2018)
  5. Bandehali S, Moghadassi A, Parvizian F, Hosseini S, Korean J. Chem. Eng., 36(10), 1657 (2019)
  6. Maarefian M, Bandehali S, Azami S, Sanaeepur H, Moghadassi A, Int. J. Energy Chem., 43, 8217 (2019)
  7. Bandehali S, Parvizian F, Moghadassi AR, Hosseini SM, Shen JN, J. Polym. Res., 27, 94 (2020)
  8. Hosseini SM, Karami F, Farahani SK, Bandehali S, Shen J, Bagheripour E, Seidypoor A, Korean J. Chem. Eng., 37(5), 866 (2020)
  9. Zinadini S, Zinatizadeh AA, Rahimi M, Vatanpour V, Zangeneh H, Beygzadeh M, Desalination, 349, 145 (2014)
  10. Bandehali S, Parvizian F, Moghadassi A, Hosseini SM, Sep. Purif. Technol., 237, 116361 (2019)
  11. Sanaeepur H, et al., Theoretical gas permeation models for mixed matrix membranes, LAP LAMBERT Academic Publishing, Beau Bassin, Mauritius (2018).
  12. Sanaeepur H, Amooghin AE, Bandehali S, Moghadassi A, Matsuura T, Van der Bruggen B, Prog. Polym. Sci, 91, 80 (2019)
  13. Ghaemi N, Madaeni SS, Daraei P, Rajabi H, Zinadini S, Alizadeh A, Heydari R, Beygzadeh M, Ghouzivand S, Chem. Eng. J., 263, 101 (2015)
  14. Bandehali S, Kargari A, Moghadassi A, Saneepur H, Ghanbari D, Asia-Pac J. Chem. Eng., 9, 638 (2014)
  15. Bandehali S, Moghadassi A, Parvizian F, Hosseini SM, Matsuura T, Joudaki E, J. Energy Chem., 46, 30 (2020)
  16. Bandehali S, Parvizian F, Moghadassi AR, Hosseini SM, J. Polym. Res., 26, 211 (2019)
  17. Bandehali S, et al., Modeling in membranes and membrane-based processes, John Wiley & Sons publications, New Jersey (2020).
  18. Daraei P, Madaeni SS, Ghaemi N, Salehi E, Khadivi MA, Moradian R, Astinchap B, J. Membr. Sci., 415, 250 (2012)
  19. Weerasekara NA, Choo KH, Choi SJ, J. Membr. Sci., 447, 87 (2013)
  20. Zangeneh H, Zinatizadeh AA, Zinadini S, Feyzi M, Bahnemann DW, React. Funct. Polym., 127, 139 (2018)
  21. Abdali N, Marjani A, Heidary F, Adimi M, New J. Chem., 41, 6405 (2017)
  22. Gholami A, Moghadassi AR, Hosseini SM, Shabani S, Gholami F, J. Ind. Eng. Chem., 20(4), 1517 (2014)
  23. Moghadassi AR, Bagheripour E, Hosseini SM, J. Appl. Polym. Sci., 134, 44993 (2017)
  24. Hosseini SM, Afshari M, Fazlali AR, Farahani SK, Bandehali S, Van der Bruggen B, Bagheripour E, Chem. Eng. Res. Des., 147, 390 (2019)
  25. Alam J, Dass LA, Ghasemi M, Alhoshan M, Polym. Compos., 34, 1870 (2013)
  26. Li CJ, Li YJ, Wang JN, Cheng J, Chem. Eng. J., 220, 294 (2013)
  27. Javaheri F, Hassanajili S, J. Appl. Polym. Sci., 133, 44330 (2016)
  28. Daraei P, Madaeni SS, Ghaemi N, Khadivi MA, Astinchap B, Moradian R, Sep. Purif. Technol., 109, 111 (2013)
  29. Pandey G, Singh S, Hitkari G, Int. Nano Lett., 8, 111 (2018)
  30. Zinadini S, Zinatizadeh AA, Rahimi M, Vatanpour V, Zangeneh H, Beygzadeh M, Desalination, 349, 145 (2014)
  31. Soares PIP, Alves AMR, Pereira LCJ, Coutinho JT, Ferreira IMM, Novo CMM, Borges JPMR, J. Colloid Interface Sci., 419, 46 (2014)
  32. Kimura K, Amy G, Drewes J, Watanabe YYJJOMS, J. Membr. Sci., 221, 81 (2003)
  33. Mohammad-Beigi H, Yaghmaei S, Roostaazad R, Bardania H, Arpanaei A, Physica E, 44, 618 (2011)
  34. Morales M, Bomati-Miguel O, De Alejo RP, Ruiz-Cabello J, Veintemillas-Verdaguer S, O’Grady K, J. Magn. Magn. Mater., 266, 102 (2003)
  35. Hoskins C, Cuschieri A, Wang L, J. Nanobiotechnol., 10, 15 (2012)
  36. Shi Q, Su YL, Zhu SP, Li C, Zhao YY, Jiang ZY, J. Membr. Sci., 303(1-2), 204 (2007)
  37. Peeva PD, Pieper T, Ulbricht M, J. Membr. Sci., 362(1-2), 560 (2010)
  38. Khan J, Tripathi BP, Saxena A, Shahi VK, Electrochim. Acta, 52(24), 6719 (2007)
  39. Hwang GJ, Ohya H, Nagai T, J. Membr. Sci., 156(1), 61 (1999)
  40. Chen SH, Liou RM, Lai CL, Hung MY, Tsai MH, Huang SL, Desalination, 234(1-3), 221 (2008)
  41. Bagheripour E, Moghadassi AR, Hosseini SM, Van der Bruggen B, Parvizian F, J. Ind. Eng. Chem., 62, 311 (2018)
  42. Bagheripour E, Moghadassi AR, Hosseini SM, Arab. J. Chem., 10, S3375 (2017)
  43. Giri A, Makhal A, Ghosh B, Raychaudhuri A, Pal S, Nanoscale, 2, 2704 (2010)
  44. Kumar SR, Marianna L, Gianni S, Nathanael AJ, Hong S, Oh TH, Mangalaraj D, Viswanathan C, Ponpandian N, Mater. Res. Express, 1, 015015 (2014)
  45. Mannan HA, Mukhtar H, Shaharun MS, Othman MR, Murugesan T, J. Appl. Polym. Sci., 133, 1 (2016)
  46. Ghaemi N, Madaeni SS, Alizadeh A, Daraei P, Vatanpour V, Falsafi M, Desalination, 290, 99 (2012)
  47. Mansourpanah Y, Madaeni SS, Rahimpour A, Adeli M, Hashemi MY, Moradian MR, Desalination, 277(1-3), 171 (2011)
  48. Parvizian F, Ansari F, Bandehali S, Chem. Eng. Res. Des., 156, 433 (2020)
  49. Bandehali S, Moghadassi A, Parvizian F, Zhang Y, Hosseini SM, Shen J, Sep. Purif. Technol., 242, 116745 (2020)
  50. Ghaemi N, Madaeni SS, Alizadeh A, Daraei P, Zinatizadeh AA, Rahimpour F, Sep. Purif. Technol., 85, 147 (2012)
  51. Bagheripour E, Moghadassi A, Hosseini SM, Asia-Pac J. Chem. Eng., 10, 791 (2015)
  52. Ghaemi N, Madaeni SS, Alizadeh A, Rajabi H, Daraei P, J. Membr. Sci., 382(1-2), 135 (2011)
  53. Peyravi M, Jahanshahi M, Rahimpour A, Javadi A, Hajavi S, Chem. Eng. J., 241, 155 (2014)
  54. Kingma AJJF, Processing B, Food Bioprod. Process., 93, 304 (2015)
  55. Lai GS, Lau WJ, Goh PS, Ismail AF, Yusof N, Tan YH, Desalination, 387, 14 (2016)
  56. Bagheripour E, Moghadassi A, Hosseini SM, Korean J. Chem. Eng., 33(4), 1462 (2016)
  57. Hegab HM, Zou LD, J. Membr. Sci., 484, 95 (2015)
  58. Zhao YY, Yuan QP, J. Membr. Sci., 279(1-2), 453 (2006)
  59. Baker RW, Membrane technology and applications, 3th Ed., John Wiley and Sons, West Sussex, UK (2012).
  60. Bandehali S, Moghadassi A, Parvizian F, Shen J, Hosseini SM, Korean J. Chem. Eng., 37(2), 263 (2020)
  61. Amirilargani M, Sadrzadeh M, Sudholter EJR, de Smet LCPM, Chem. Eng. J., 289, 562 (2016)
  62. Madaeni SS, Zinadini S, Vatanpour V, Sep. Purif. Technol., 111, 98 (2013)
  63. Mansourpanah Y, Rahimpour A, Tabatabaei M, Bennett L, Desalination, 419, 79 (2017)