화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.89, 368-374, September, 2020
DOI10.1016/j.jiec.2020.06.005  Export Citation
Calcination of layered double hydroxide membrane with enhanced nanofiltration performance
Zheng Huang, Naixin Wang†, Xiaoting Li, and Quan-Fu An
  • Beijing Key Laboratory for Green Catalysis and Separation, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, PR China
E-mail:
Two-dimensional layered double hydroxides (LDH) as a membrane material has tremendous potential in the water treatment field. However, the stability and permeance of the LDH membrane should be further improved for the industrial application. In this study, the LDH separation layer was in situ grown on the tubular Al2O3 substrate. The obtained LDH composite membrane was then calcined to reduce the surface free energy and remove some interlayer anions. Therefore, the calcined LDH composite membrane exhibited enhanced stability and permeance for removing dye molecules from water. The permeance of the calcined LDH membrane reached 367 L m-2 h-1MPa-1 and the rejection for Eriochrome black T was still above 99%. Moreover, the membrane can maintain the separation performance more than 110 h in the nanofiltration process. The morphologies and structures of the LDH membranes before and after calcination were also investigated. The results indicated that this facile method is effective to improve the separation performance of the LDH membrane.
Keywords:Layered double hydroxide;Nanofiltration;Calcination;Surface free energy;Enhanced performance
  1. Mohammad AW, Teow YH, Ang WL, Chung YT, Oatley-Radcliffe DL, Hilal N, Desalination, 356, 226 (2015)
  2. Stevens DM, Shu JY, Reichert M, Roy A, Ind. Eng. Chem. Res., 56(38), 10526 (2017)
  3. Fan L, Zhang Q, Yang Z, Zhang R, Liu Y, He M, Jiang Z, Su Y, ACS Appl. Mater. Interfaces, 9, 13577 (2017)
  4. Wang L, Guo X, Cao K, Li B, Li Y, Zhang M, Wen R, Li X, Li S, Ma L, J. Mater. Chem. A, 5, 8051 (2017)
  5. Mohammad AW, Teow YH, Ang WL, Chung YT, Oatley-Radcliffe DL, Hilal N, Desalination, 356, 226 (2015)
  6. Yuan S, Li X, Zhu J, Zhang G, Puyveldeb PV, Bruggen BVD, Chem. Soc. Rev., 48, 2665 (2019)
  7. Anand A, Unnikrishnan B, Mao JY, Lin HJ, Huang CC, Desalination, 429, 119 (2018)
  8. Han Y, Jiang Y, Gao C, ACS Appl. Mater. Interfaces, 15, 8147 (2015)
  9. Yuan YQ, Gao XL, Wei Y, Wang XY, Wang J, Zhang YS, Gao CJ, Desalination, 405, 29 (2017)
  10. Peng Y, Li Y, Ban Y, Jin H, Jiao W, Liu X, Yang W, Science, 346, 1356 (2017)
  11. Liu Y, Wang NY, Pan JH, Steinbach F, Caro J, J. Am. Chem. Soc., 136(41), 14353 (2014)
  12. Bux H, Chmelik C, van Baten JM, Krishna R, Caro J, Adv. Mater., 22(42), 4741 (2010)
  13. Ding L, Wei Y, Wang Y, Chen H, Caro J, Wang H, Angew. Chem.-Int. Edit., 56, 1825 (2017)
  14. Pandey RP, Rasool K, Madhavan VE, Aissa B, Gogotsi Y, Mahmoud KA, J. Mater. Chem. A, 6, 3522 (2018)
  15. Ding L, Wei Y, Li L, Zhang T, Wang H, Xue J, DinG L, Wang S, Caro J, Gogotsi Y, Nat. Commun., 9, 155 (2018)
  16. Kandambeth S, Biswal BP, Chaudhari HD, Rout KC, Kunjattu HS, Mitra S, Karak S, Das A, Mukherjee R, Kharul UK, Banerjee R, Adv. Mater., 29, 160394 (2017)
  17. Halder A, Karak S, Addicoat M, Bera S, Chakraborty A, Kunjattu SH, Pachfule P, Heine T, Banerjee R, Angew. Chem.-Int. Edit., 57, 5899 (2018)
  18. Chen L, Shi G, Shen J, Peng B, Zhang B, Wang Y, Bian F, Wang J, Li D, Qian Z, et al., Nature, 550, 380 (2017)
  19. Lu P, Liang S, Qiu L, Gao YS, Wang Q, J. Membr. Sci., 504, 196 (2016)
  20. Pardeshi PM, Mungray AK, Mungray AA, Desalination, 421, 149 (2017)
  21. Wang Q, O'Hare D, Chem. Rev., 112(7), 4124 (2012)
  22. Zhao MQ, Zhang Q, Huang JQ, Wei F, Adv. Funct. Mater., 22(4), 675 (2012)
  23. Li C, Wei M, Evans DG, Duan X, Small, 10, 4469 (2014)
  24. Liu Y, Wang NY, Cao ZW, Caro J, J. Mater. Chem. A, 2, 5716 (2014)
  25. Liu Y, Wang NY, Cao ZW, Caro J, J. Mater. Chem. A, 2, 1235 (2014)
  26. Lu P, Liu Y, Zhou TT, Wang Q, Li YS, J. Membr. Sci., 567, 89 (2018)
  27. Fan HW, Peng MH, Strauss I, Mundstock A, Meng H, Caro J, J. Am. Chem. Soc., 142(15), 6872 (2020)
  28. Liu Y, Matsuda R, Kusaka S, Hori A, Ma Y, Kitagawa S, CrystEngComm, 20, 6995 (2018)
  29. Wang N, Huang Z, Li X, Li J, Ji S, An Q, J. Mater. Chem. A, 6, 17148 (2018)
  30. Hibino T, Ohya H, Appl. Clay Sci., 45, 123 (2009)
  31. Li H, Tran T, Lee B, Zhang C, Park J, Kang T, Yu J, ACS Appl. Mater. Interfaces, 9, 20194 (2017)
  32. Hilal N, Al-Zoubi H, Darwish NA, Mohammad AW, Abu Arabi M, Desalination, 170(3), 281 (2004)
  33. Santos RMM, Tronto J, Briois V, Santilli CV, J. Mater. Chem. A, 5, 9998 (2017)
  34. Yang WS, Kim Y, Liu PKT, Sahimi M, Tsotsis TT, Chem. Eng. Sci., 57(15), 2945 (2002)
  35. Li X, Wang N, Huang Z, Zhang L, Xie Y, An Q, Ji S, J. Mater. Chem. A, 6, 18095 (2018)
  36. Ma H, Xie Q, Wu C, Shen L, Hong Z, Zhang G, Lu Y, Shao W, J. Membr. Sci., 590, 117268 (2019)
  37. Warringham R, Mitchell S, Murty R, Schaublin R, Crivelli P, Kenvin J, Ramirez JP, Chem. Mater., 29, 4052 (2017)
  38. Li Z, Yang B, Zhang S, Wang B, Xue B, J. Mater. Chem. A, 2, 10202 (2014)
  39. Wang N, Li Q, Li X, Zhang W, Ji S, An Q, J. Membr. Sci., 603, 118032 (2020)