화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.28, No.10, 948-952, September, 2020
DOI10.1007/s13233-020-8130-0  Export Citation
Facile Preparation of Polymer-Grafted Halloysite Nanotubes via a Redox System: a Novel Approach to Construct Antibacterial Hydrogel
Yanfang Ma, Zhihang Zhao1, Boyan Tang1, Yonggang Wu1, and Hailei Zhang1, †
  • Shijiazhuang Institute of Railway Technology, Shijiazhuang, P. R. China
  • 1College of Chemistry and Environmental Science, Hebei University, Baoding, P. R. China
E-mail:
We demonstrate the use of a supernormal valence transition-metal (Ce(IV) and Cu(III))-mediated redox system for the surface grafting on the halloysite nanotubes (HNTs). Following this way, commonly-used vinyl monomers were grafted on HNTs in one step under mild condition. The grafting was evidenced using FTIR, X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). The micro-morphology was carefully characterized by transmission electron microscope (TEM). The results indicate that the surface grafting reaction was successfully processed in all cases, in which the Ce(IV) shows a much higher initiation activity than that of Cu(III). Then a uniform hydrogel was constructed by mixing poly(triethyl(4-vinylbenzyl)phosphonium chloride-grafted HNTs (HNTs-P(Et-P)) with sodium polyacrylate-grafted HNTs (HNTs-P(AA-Na)), which show desirable antibacterial activity.
Keywords:halloysite nanotubes;clay;surface grafting;hydrogel;antibacterial
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