Hierarchical-Beta zeolites have been hydrothermally synthesized by adding a new gemini organic surfactant. The used gemini surfactant play the role of a "pore-forming agents " on the mesoscale, on the same time, providing alkaline environment for the system. With this hierarchical Beta zeolite as the core support, we successfully prepared a shell layer of Nicontaining (22 wt%) petal-like core-shell-like catalyst and applied it to bioethanol steam reforming. At the reaction temperature of 350 degrees C-550 degrees C, the conversion rate of ethanol and the selectivity of hydrogen were always above 85% and 70%. After reaction of 100 h on stream at 400 degrees C, there were not obvious inactivation could be observed on NiNPs/OH-MBeta catalyst. (C) 2020 Published by Elsevier Ltd on behalf of Hydrogen Energy Publications LLC.