The photocatalytic hydrogen generation is a novel, eco-friendly and favourable method for production of green and clean energy using light energy. In this direction, we report low-temperature ionothermal method for the preparation of TiO2 nanoparticles (NPs) using methoxy ethyl methyl imidazolium tris (pentafluoroethyl) trifluoro phosphate (MOEMINtf(2)) as an ionic liquid (IL) at 120 degrees C for 1 day. The synthesized nanomaterials were examined using different spectrochemical methods like UV-DRS, XRD, FT-IR, TEM, BET and TGA-DTA techniques. The mixed phase TiO2 is obtained with 81.7% of anatase and 18.3% of rutile phase by the XRD studies, and average crystallite size is found to be similar to 7 nm. The stretching of Ti-O bond (similar to 555 cm(-1)) and few other bands related to ionic liquid were confirmed by FTIR spectrum. The band gap energy was observed to be similar to 3.38 eV by UV-DRS analysis. TEM images reveal spherical shape with an average particles size of about 10 nm. Photocatalytic H-2 generation was carried out using TiO2 NPs and observed the generation of 553 mu mol h(-1) g(-1) via water splitting reaction. Furthermore, the prepared TiO2 NPs employed for the photocatalytic degradation of methylene blue dye (84.54%), and photoluminescence studies confirms the obtained material can be used in optoelectronic applications with green emission.