NOx and CO formation is, at present, a consequence arising from fuel production, but their emission need not be. In this study, a series of novel Ir-containing TiO2 nanobelt catalysts were designed and prepared for the simultaneous removal of NOx and CO. Activity data demonstrates that the TiO2 (B) support promotes NO reduction compared to anatase. Furthermore, reaction efficiency (RE), a measure of NQ consumption vis-a-vis that of CO, reveals that catalysts containing anatase promote CO oxidation more so than their TiO2 (B) counterparts. Increasing Ir concentration over the latter promotes low-temperature catalytic performance, an effect believed to be linked to the formation of Ir-0-IrO2 composites. In situ DRIFTS experiments reveal the relevance of nitrite/nitrate formation and consumption at 250 degrees C, a mechanism insinuated by the RE value. However, at 300 degrees C, both TOF and RE increase, signifying the participation of a faster and more-selective reaction, which appears consistent with the isocyanate-mediated pathway.