화학공학소재연구정보센터
Catalysis Today, Vol.346, 40-45, 2020
Sustainable process for adipic acid production from cyclohexene in microemulsion
Adipic acid appears as an intermediate compound for the synthesis of polyamides and preferentially for the production of nylon-6,6 polyamide. It can be synthesized by the oxidation of cyclohexene by hydrogen peroxide in microemulsion media which has the main advantage to lead a better contact between the two phases thus increasing the yield of the reaction. The microemulsion is generated by stearyl dimethyl benzyl ammonium chloride (C18) as a surfactant avoiding the use of harmful organic solvents and phase-transfer catalysts. The reaction is performed under mild conditions (85 degrees C, 8 h) with sodium tungstate, - a no heavy metal catalyst leading to the production of adipic acid in high yield (> 80%). By recycling the catalyst and the surfactant, the process becomes truly green.