화학공학소재연구정보센터
AIChE Journal, Vol.45, No.7, 1576-1586, 1999
Use of hydration and dissociation chemistries with the electrolyte-NRTL model
Sound theoretical understanding and accurate mathematical representation of electrolyte solution nonideality were the subject of extensive research efforts for decades. It is demonstrated that these goals can be achieved by incorporation of hydration and partial dissociation chemistries with the semi-empirical electrolyte NRTL model. The resulting model provides a comprehensive thermodynamic framework for accurate correlation and reliable extrapolation of electrolyte solution nonideality over the entire concentration range.