화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.87, 130-135, July, 2020
DOI10.1016/j.jiec.2020.03.023  Export Citation
Polyacetylene polyelectrolyte via the non-catalyst polymerization of 2-ethynylpyridine using heptafluorobenzyl iodide
Taehyoung Kim, Sung-Ho Jin1, Jongwook Park2, Kwon Taek Lim3, Sang Youl Kim, and Yeong-Soon Gal4
  • Department of Chemistry, Korea Advanced Institute of Science and Technology, Daejon 34141, Republic of Korea
  • 1Department of Chemistry Education, Pusan National University, Busan 46279, Republic of Korea
  • 2Department of Chemical Engineering, Kyunghee University, Suwon 17104, Republic of Korea
  • 3Department of Display Engineering, Pukyong National University, Busan 48513, Republic of Korea
  • 4Department of Fire Safety, Kyungil University, Gyeongsan 38428, Gyeongsangbuk-Do, Republic of Korea
A new ionic polyacetylene having perfluorinated benzyl substituent, poly(2-ethynyl-N-heptafluor- obenzylpyridinium iodide), was synthesized via the direct polymerization of the quaterinazed acetylenic pyridinium monomers. The polymerization proceeded homogeneously without any additional initiator or catalyst to give a moderate yield of polymer. The results of instrumental analyses on the molecular structure of polymer revealed that the polymer have polyacetylene backbone system with Nheptafluorobenzylicpyridinium iodide as substituent. The photoluminescence (PL) spectra of polymer exhibited that the PL peak is located at 550 nm, corresponding to a photon energy of 2.26 eV. The irreversible electrochemical behaviors of polymer between the doped and undoped peaks were observed in the cyclic voltammograms of polymer. The initial oxidation and reduction of poly(EHFBPI) occurred at 0.53 V and -0.75 V (vs Ag/AgNO3). HOMO level of poly(EHFBPI) was 5.27 eV.
Keywords:Polyacetylene;Conjugated polymer;2-Ethynylpyridine;Heptafluorobenzyl iodide;Photoluminescence;Cyclic voltammogram
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