화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.44, No.3, 270-280, May, 2020
DOI10.7317/pk.2020.44.3.270  Export Citation
재활용 폴리에틸렌테레프탈레이트/폴리에틸렌 블렌드의 비등온 결정화 거동과 유변학 및 열전도 특성
Non-isothermal Crystallization Behavior, Rheological and Thermal Conductive Properties of Recycled Polyethylene Terephthalate/Polyethylene Blends
Bin Yang†, Dan Wang, Qin-Ting Chen, Jin Chen, Kang Chen, Ji-Bin Miao, Jia-Sheng Qian, Ru Xia, and You Shi1
  • College of Chemistry & Chemical Engineering, Institute of High Performance Rubber Materials & Products, and Key Laboratory of Environment-Friendly Polymeric Materials of Anhui Province, Anhui University, Hefei 230601, China
  • 1College of Polymer Science & Engineering, State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, Sichuan, China
E-mail:
In this study, we prepared series of recycled polyethylene terephthalate (RPET)/polyethylene (PE) blends using melt extrusion. The effect of RPET content on crystallization behavior and thermal conductive properties of the resultant blends were investigated using differential scanning calorimetry (DSC), dynamic mechanical thermal analysis (DMTA), etc. RPET was found to exert nucleating effect on the melt crystallization of PE. The Agari model presented fairly reasonable prediction of thermal conductivity as a function of RPET loading. The melt cooling process was predicted with an enthalpy transformation method (ETM), which is a well-established mean of evaluating the instantaneous heat conduction of crystalline polymers/composites, and the obtained curves were consistent with our experimental results. Besides, a four-parameter model (FPM) was adopted coupled with an in-situ temperature measurement in order to further disclose the solidification and crystallization kinetics of PE in the presence of RPET in the blends.
Keywords:melt blending;thermal properties;cooling behavior;recycled polyethylene terephthalate;polyethylene
  1. Yıldırım S, Pehlivan K, Durmus A, Esmer K, Polym. Korea, 42(5), 769 (2018)
  2. Ahn Y, Jeon JH, Park JH, Thenepalli T, Ahn JW, Han C, Korean J. Chem. Eng., 33(11), 3258 (2016)
  3. Kim KH, Jung DH, Han JG, Kim JH, Polym. Korea, 42(1), 8 (2018)
  4. Kim HN, Yang YK, Hwang KS, Ha KR, Polym. Korea, 41(6), 1011 (2017)
  5. Li SC, Lu LN, J. Appl. Polym. Sci., 108(6), 3559 (2008)
  6. Choi YS, Jeon HY, Polym. Korea, 39(3), 475 (2015)
  7. Kwak YJ, Seo JH, Lee SW, Polym. Korea, 42(3), 456 (2018)
  8. Tasic A, Rusmirovic JD, Nikolic J, Bozic A, Pavlovic V, Marinkovic AD, Uskokovic PS, J. Compos. Mater., 51, 491 (2016)
  9. Lee S, Kang S, Kim JH, Polym. Korea, 41(2), 287 (2017)
  10. Yang WJ, Chang JH, Polym. Korea, 39(5), 746 (2015)
  11. Fang C, Yang R, Zhang ZS, Zhou X, Lei WQ, Cheng YL, Zhang W, Wang D, RSC Adv., 8, 8920 (2018)
  12. Choi S, Jeong Y, Polym. Korea, 38(2), 240 (2014)
  13. Allen NS, Edge M, Mohammadian M, Jones K, Polym. Degrad. Stabil., 43, 229 (1994)
  14. Sharma R, Bansal PP, J. Clean Prod., 112, 473 (2016)
  15. Blom HP, The JW, Rudin A, J. Appl. Polym. Sci., 70, 2081 (2015)
  16. Entezam M, Aghjeh MKR, Ghaffari M, Radiat. Phys. Chem., 131, 22 (2017)
  17. Lubna MM, Salem KS, Sarker M, Khan MA, J. Polym. Environ., 26, 83 (2018)
  18. Kordjazi Z, Ebrahimi NG, J. Appl. Polym. Sci., 116(1), 441 (2010)
  19. Shields RJ, Bhattacharyya D, Fakirov S, J. Mater. Sci., 43(20), 6758 (2008)
  20. Chen RS, Ahmad S, Gan S, Compos. Part B-Eng., 131, 91 (2017)
  21. Park YW, Park M, Kim HY, Kim HC, Lim JC, Jin FL, Park SJ, Bull. Mater. Sci., 41, 104 (2018)
  22. Raffa P, Coltelli M, Castelvetro V, J. Appl. Polym. Sci., 131, 5829 (2014)
  23. Chen RS, Ahmad S, Gan S, Polym. Compos., 39, 2695 (2018)
  24. Hassan NRN, Ismail NM, Ghazali S, Nuruzzaman DM, IOP Conf. Ser.: Mater. Sci. Eng., 342, 012094 (2018)
  25. Sombatdee S, Amornsakchai T, Saikrasun S, Polym. Adv. Technol., 29, 1123 (2018)
  26. Yang B, Miao JB, Min K, Xia R, Qian JS, Wang X, J. Appl. Polym. Sci., 128(3), 1922 (2013)
  27. Yang B, Xia R, Miao JB, Qian JS, Yang MB, Chen P, Polym. Test, 32, 202 (2013)
  28. Yang B, Ding MY, Shi Y, Hu L, Xia R, Miao JB, Cao M, Qian JS, Chen P, Zhang YC, Fu EF, J. Appl. Polym. Sci., 136, 47390 (2018)
  29. Yang B, Hu L, Xia R, Chen F, Zhao SC, Deng YL, Cao M, Qian JS, Chen P, Macromol. Res., 24(1), 74 (2016)
  30. Hu L, Yang B, Deng YL, Lu FX, Xia R, Zheng ZZ, Miao JB, Qian JS, Zhang CR, Chen P, Zhang YC, Polym. Korea, 41(4), 569 (2017)
  31. Li HB, Li Q, Yan ML, Adv. Mater. Res., 291, 1820 (2011)
  32. Shi Y, Yang B, Miao JB, Zheng ZZ, Qian JB, Su LF, Cao M, Xia R, Chen P, Liu JW, Li GJ, Polym. Crystal, 2 (2019)
  33. Zakani B, Ansari M, Grecov D, Rheol. Acta, 57(1), 83 (2018)
  34. Chun MS, Ko MJ, J. Korean. Phys. Soc., 61, 1108 (2012)
  35. Nouri S, Dubois C, Lafleur PG, Polymer, 67, 227 (2015)
  36. Zarandi MB, Bioki HA, Mirbagheri ZA, Tabbakh F, Mirjalili G, Appl. Radiat. Isotopes., 70, 1 (2012)
  37. Granado A, Eguiazabal JI, Nazabal J, Macromol. Mater. Eng., 289, 997 (2004)
  38. Martins JN, Bianchi O, Wanke CH, Castel CD, Oliveira RVB, J. Polym. Res., 22, 224 (2015)
  39. Ferreira CI, Dal Castel C, Oviedo MAS, Mauler RS, Thermochim. Acta, 553, 40 (2013)
  40. Papageorgiou GZ, Achilias DS, Nanaki S, Beslikas T, Bikiaris D, Thermochim. Acta, 511(1-2), 129 (2010)
  41. Khanna YP, Polym. Eng. Sci., 30, 1615 (1990)
  42. Avrami M, J. Chem. Phys., 8, 212 (1940)
  43. Elamri A, Lallam A, Harzallah O, Bencheikh L, J. Mater. Sci, 42, 8271 (2007)
  44. Vasiljevic-Shikaleska A, Popovska-Pavlovska F, Cimmino S, Duraccio D, Silvestre C, J. Appl. Polym. Sci., 118(3), 1320 (2010)
  45. Kiziltas A, Gardner DJ, Han Y, Yang HS, J. Therm. Anal. Calorim., 103, 163 (2011)
  46. Zhang YH, Choi JR, Park SJ, Compos. Part A-Appl. S., 109, 498 (2018)
  47. Safri SNA, Sultan MTH, Jawaid M, Majid MSA, Compos. Struct., 226, 111308 (2019)
  48. Miranda LF, Silveira LH, Andrade e Silva LG, Munhoz AH, Adv. Sci. Technol., 71, 138 (2010)
  49. Liu YH, Bai LB, Zhou WQ, Liu YW, Tang MY, Deng KL, Iran. Polym. J., 14, 891 (2005)
  50. Zeus Industrial Products, Inc., Performance of High Temperature Plastics, Technical whitepaper, 1 (2005).
  51. Shields RJ, Bhattacharyya D, Fakirov S, Compos. Part A Appl. S., 39, 940 (2008)
  52. Li ZM, Yang W, Xie BH, Huang R, Yang MB, Feng JM, J. Macromol. Sci. B, 43, 519 (2004)
  53. Xia R, Sun MM, Yang B, Qian JS, Chen P, Cao M, Miao JB, Su LF, Polym. Korea, 42, 229 (2018)
  54. Agari Y, Ueda A, Nagai S, J. Appl. Polym. Sci., 42, 1665 (1991)
  55. Yang B, Guo YD, Xia R, Miao JB, Su LF, Qian JS, Chen P, Zhang QL, J. Macromol. Sci. B, 55, 99 (2016)
  56. Liang SP, Yang B, Fu XR, Yang W, Sun N, Hu S, Yang MB, J. Appl. Polym. Sci., 117(2), 729 (2010)
  57. Deng SQ, Yang B, Miao JB, Xia R, Qian JS, Chen P, Yang MB, J. Polym. Eng., 32, 355 (2012)
  58. Yang B, Fu XR, Yang W, Huang L, Yang MB, Feng JM, Polym. Eng. Sci., 48(9), 1707 (2008)
  59. Yang B, Hu L, Li GJ, Zhang CR, Miao JB, Xia R, Su LF, Deng YL, Qian JS, Chen P, Plast. Rubber. Compos., 46, 200 (2017)
  60. Yang B, Ding MY, Hu L, Li GJ, Miao JB, Gao X, Li XB, Zhang B, Su LF, Chen P, Qian JS, J. Macromol. Sci. B, 58, 42 (2019)