Water is the essential liquid on earth since it not only plays vital roles in living systems but also has a significant impact on our daily life from various industrial applications to earth's climate system. However, the unusual properties of liquid water, if compared with other liquids, has puzzled us for centuries because the basic structure of liquid water has remained unclear and has continued to be a matter of serious debate. Here, by computer simulations of three popular water models and the analysis of recent scattering experimental data, we show that there are two overlapped peaks hidden in the apparent "first diffraction peak" of the structure factor. One of them (ordinary peak) corresponds to the neighboring O-O distance as in ordinary liquids, and the other (anomalous peak) corresponds to a longer distance. We reveal that this anomalous peak arises from the most extended period of density wave associated with a tetrahedral water structure and is to be identified as the so-called first sharp diffraction peak that is commonly observed in silica and other tetrahedral liquids. In contrast, the ordinary peak arises from the density wave characteristic of local structures lacking tetrahedral symmetry. This finding unambiguously proves the coexistence of two types of local structures in liquid water. Our findings not only provide vital clues to settle a long-standing controversy on the water structure but also allow direct experimental access to the fraction of tetrahedral structures in liquid water.