A global potential energy surface for the lowest quartet state of HN2 is reported for the first time from accurate multireference ab initio calculations extrapolated to the complete basis set limit using the double many-body expansion method. All its stationary points are characterized, with the lowest quartet of HN2 predicted to have a bent global minimum 36 kcal Tel mol(-1) below the N(S-4) + NH((X) over tilde (3)Sigma(-)) asymptote, from which it is barrierlessly achievable. The entire set of calculated ab initio points has been fitted for energies up to 1000 kcal mol(-1) above the global minimum with an RMSD of 0.89 kcal mol(-1), a gap comprising all identified stationary points. Special care is taken in modeling the involved long-range forces and cusps caused by crossing seams. The novel PES prompts for the calculation of rate constants for several unexplored reactions that are relevant for combustion, plasma, and atmospheric chemistry.