Journal of the Electrochemical Society, Vol.142, No.11, 3859-3863, 1995
Photochemical Dry-Etching of Doped and Undoped Silicon-Oxides
The photochemical dry etching of doped and undoped silicon oxides with ClF3 and F-2 gas has been investigated. Etching rates of several hundred angstroms per minute have been achieved with bulk substrate temperatures below 300 degrees C. Borophosphosilicate glass-to-thermal oxide etching rate selectivity is near 1-to-1 over a wide range of process conditions; The addition of Cl-2 gas is found to significantly reduce the etching rates of both doped and undoped silicon oxide under these conditions. The photochemical dry cleaning of a 10 to 20 A chemical oxide layer from trench and via bottoms is discussed.
Keywords:TEMPERATURE;HYDROGEN