A heterogeneous photocatalyst has been developed using sono-chemical assisted sol-gel method by maintaining aweight ratio of 1:2:3 for hydrogen exfoliation graphene, titanium oxide andcopper sulphateand exhaustively characterized. Rigorous experimentations have been done using newly developed heterogeneous photocatalyst for efficient capturing and maximum conversion of carbon di oxide to methanol by mutual effects of governing conditions, like as catalyst dose, pH, CO2 flow rate and temperature. Optimization study has been carried out employing a statistical approach of response surface methodology which reveals the maximum methanol productivity and yield. Approximately, 134 g/Lh of productivity and 40 mg/g(cat) of yield were found after 3 h of illumination under UV in an annular type Pyrex reactor at an optimum catalyst dosage of 10 g/L, CO2 flow rate of 3 L/m, pH of 3, and process temperature of 50 degrees C. By the judicial integration of flat-sheet cross flow microfiltration membrane module for catalyst separation and recycle, a steady state permeate flux 145 L/m(2)h was achieved at an applied pressure of 3 bar and cross-flow feed rate of 700 L/h. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.