Korean Journal of Materials Research, Vol.30, No.4, 176-183, April, 2020
CaCl2-CaF2-CaO 용융염에서 YSZ 세라믹의 고온 안정성에 미치는 성형공정의 영향
Effect of Pressing Process on the High-Temperature Stability of Yttria-Stabilized Zirconia Ceramic Material in Molten Salt of CaCl2-CaF2-CaO
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The high-temphigh-temperature stability, yttria stabilized zirconia, solid oxide membrane, degradation, molten salterature stability of YSZ specimens fabricated by die pressure and cold isostatic press (CIP) is investigated in CaCl2-CaF2-CaO molten salt at 1,150 °C. The experimental results are as follows: green density 46.7 % and 50.9 %; sintering density 93.3 % and 99.3 % for die press and CIP, respectively. YSZ foremd by CIP exhibits higher stability than YSZ formed by die press due to denseness dependency after high-temperature stability test. YSZ shows peaks mainly attributed to CaZrO3, with a small t-ZrO2 peak, unlike the high-intensity tetragonal-ZrO2 (t-ZrO2) peak observed for the asreceived specimen. The t-ZrO2 phase of YSZ is likely stabilized by Y2O3, and the leaching of Y2O3 results in phase transformation from t-ZrO2 to m-ZrO2. CaZrO3 likely forms from the reaction between CaO and m-ZrO2. As the exposure time increases, more CaZrO3 is observed in the internal region of YSZ, which could be attributed to the inward diffusion of molten salt and outward diffusion of the stabilizer (Y2O3) through the pores. This results in greater susceptibility to phase transformation and CaZrO3 formation. To use SOM anodes for the electroreduction of various metals, YSZ stability must be improved by adjusting the high-density in the forming process.
Keywords:high-temperature stability;yttria stabilized zirconia;solid oxide membrane;degradation;molten salt
- Das S, JOM, 60, 63 (2008)
- Krishnan A, Lu XG, Pal UB, Metall. Mater. Trans. B-Proc. Metall. Mater. Proc. Sci., 36, 463 (2005)
- Selvasekarapandian S, Bhuvaneswari MS, Vijayakumar M, Ramya CS, Angelo PC, J. European Ceram. Soc., 25, 2573 (2005)
- Brett DJL, Atkinson A, Brandon NP, Skinner SJ, Chem. Soc. Rev., 37, 1568 (2008)
- Gao YM, Wang B, Wang SB, Peng S, J. Min. Metall. B Metall., 49B, 49 (2013)
- Aytimur A, Uslu I, Kocyigit S, Ozcan F, Ceram. Int., 38, 3851 (2012)
- McHale AE, Phase Diagrams for Ceramists Annual 91/Phan91, 146, J Am Ceram Soc, inc. Westervile, USA (1991).
- Milshtein J, Gratz E, Pati S, Powell AC, Pal UB, J. Min. Metall. B Metall., 49B, 183 (2013)
- Suzuki RO, J. Phys. Chem. Solids, 66, 461 (2005)
- Alexander DTL, Schwandt C, Fray DJ, Acta Mater., 54, 29334 (2006)
- Takeda O, Okabe TH, Metall. Mater. Trans. B-Proc. Metall. Mater. Proc. Sci., 1, 160 (2014)
- Chowdhury KMS, Akbar SA, Kapileshwar S, Schorr JR, J. Electrochem. Soc., 148, 146 (2001)
- Pal UB, Woolley DE, Kenney GB, JOM, 53, 32 (2001)
- Ajay K, Thesis (Ph.D.), Boston University, Boston (2006).
- Li S, Zou X, Zheng K, Lu X, Xu Q, Chen C, Zhou Z, J. Alloy. Compd., 727, 1243 (2017)
- Pal UB, Powell AC, JOM, 59, 44 (2007)
- Lu X, Zou X, Li C, Zhong Q, Ding W, Zhou Z, Metall. Mater. Trans. B-Proc. Metall. Mater. Proc. Sci., 43, 503 (2012)
- Zou XL, Lu XG, Li CH, Zhou ZF, Electrochim. Acta, 55(18), 5173 (2010)
- Zou XL, Lu XG, Zhou ZF, Li CH, Ding WZ, Electrochim. Acta, 56(24), 8430 (2011)
- Zhao BJ, Lu XG, Zhong QD, Li CH, Chen SL, Electrochim. Acta, 55(8), 2996 (2010)
- Kwon SC, Cho SH, Nersisyan HH, Lee JH, Kang JS, Lee JH, Am. Ceram. Soc., 101, 2074 (2018)
- Pal UB, JOM, 60, 43 (2008)
- Martin A, Lambertin D, Poignet JC, Allibert M, Bourges G, Pescayre L, Fouletier J, JOM, 55, 52 (2003)
- Guan X, Pal UB, Prog. Nat. Sci. Mater., 25, 591 (2015)
- Ye XS, Lu XG, Li CH, Ding WZ, Zou XL, Gao YH, Zhong QD, Int. J. Hydrog. Energy, 36(7), 4573 (2011)
- Chen GZ, Fray DJ, Farthing TW, Nature, 407, 361 (2000)
- Yoo BU, Kwon SC, Cho SH, Nersisyan HH, Lee JH, J. Alloy. Compd., 771, 924 (2019)
- Suput M, Delucas R, Pati S, Ye G, Pal U, Powell AC, Miner. Process Extract Metall., 117, 118 (2008)
- Gemmen R, Abernathny H, et al., Ceramic Engineering and Science Proceedings, Wiley and Sons, Hoboken, NJ, p. 37-46 (2009).
- Stournaras CJ, Tsetsekou A, Zambetakis T, Kontoyannis CG, Carountzos G, J. Mater. Sci., 30(17), 4375 (1995)
- Kontoyannis CG, Carountzos G, Stournaras CJ, Tsetsekou A, J. Mater. Sci. Lett., 15(3), 222 (1996)
- Martin A, Poignet JC, Fouletier J, Allibert M, Lambertin D, Bourges G, J. Appl. Electrochem., 40(3), 533 (2010)
- Gratz ES, Milshtein JD, Pal U, J. Am. Ceram. Soc., 96, 3279 (2013)
- Xu J, Lo B, Jiang Y, Pal U, Basu S, J. European Ceram. Soc., 34, 3887 (2014)
- Gratz ES, Milshtein JD, Pal UB, J. Am. Ceram. Soc., 96, 3279 (2013)
- Ingel RP, Lewis D, J. Am. Ceram. Soc., 69, 325 (1986)
- Xu Z, He L, Mu R, He S, Huang G, Cao X, Surf. Coat. Technol., 204, 3652 (2010)
- Raheleh AP, Reza SR, Reza M, Hossein J, Ceram. Int., 38, 6613 (2012)