화학공학소재연구정보센터
Journal of the Electrochemical Society, Vol.142, No.1, 249-254, 1995
Solid-State Hydrogen Sensors Using Palladium-Nickel Alloys - Effect of Alloy Composition on Sensor Response
Thin film alloys of Pd and Ni make good sensors for hydrogen partial pressures (pH(2)) over a very wide range : from 10(-3) to 700 Torr. For pH(2) from 1 to 700 Torr the atomic percent of Ni in the alloy has a strong effect on the change in film resistance which is used as the sensing property. The phase transition from the alpha- to the hydride beta-phase must be avoided to maintain a reversible sensor. The characteristics of alloys with Ni of 3, 5.3, 8, and 15% are reported. The phase transition was found in the 5.3% alloy at about 250 Torr, but alloys of Ni > 8% showed no phase change behavior up to 630 Torr (pure H-2) at ambient temperatures. Other characteristics of the Pd/Ni alloy sensors are also reported, including the effect of temperature, oxygen, and relative humidity, and the speed of response to step changes in pH(2).