The synthesis and characterisation of the highly stable perovskite nano crystals and their application to ink-jet printed colour conversion layers

Sol Choi; Sang Yoon Lee; Do Yeob Kim; Hyung-Ki Park; Min Jae Ko; Kwan Hyun Cho; Jun Choi

Journal of Industrial and Engineering Chemistry, Vol.85, 226-239, May, 2020

DOI10.1016/j.jiec.2020.02.005 Export Citation

The synthesis and characterisation of the highly stable perovskite nano crystals and their application to ink-jet printed colour conversion layers

Sol Choi^{1, 2}, Sang Yoon Lee^{1, 3}, Do Yeob Kim⁴, Hyung-Ki Park⁵, Min Jae Ko^{2, †}, Kwan Hyun Cho^{4, †}, and Jun Choi^{1, †}

¹Human Convergence Technology Group, Korea Institute of Industrial Technology, Ansan-si, Gyeonggi-do, 15588, Republic of Korea
²Department of Chemical Engineering, Hanyang University, Wangsimni-ro, Seongdong-gu, 222, Seoul, Republic of Korea
³Department of Advanced Material Engineering for Information & Electrices, Kyunghee University, 1732, Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do, Republic of Korea
⁴Micro/Nano Scale Manufacturing R&D Group, Korea Institute of Industrial Technology, Ansan-si, Gyeonggi-do, 15588, Republic of Korea
⁵Gangwon Regional Division, Korea Institute of Industrial Technology, Gangneung, 25440, Republic of Korea

E-mail:, ,

We synthesised cesium lead bromide and formamidinium lead bromide perovskite colloidal nanocrystals by ligand-assisted reprecipitation method for the wide-colour gamut low-cost displays. The prepared perovskite colloidal nanocrystal solutions were formulated into the ink-jet printable homogeneous inks and uniformly coated as the colour conversion layers of the quantum dot organic light-emitting diode displays. The silica capped CsPbBr3 nanocrystals were very stable in high temperature observation while the FAPbBr3 showed the excellent long-term stability at room temperature even without the silica passivation. The ink-jet printed colour conversion films had very narrow full-width-at-half-maximums of around 20 nm and high photoluminescence quantum yields of 73.0% and 76.9%, respectively. Particularly, the FAPbBr3 thin film had an excellent cut-off ratio of blue emission and exhibited external quantum efficiency of 5.39% when fabricated as the hybrid display devices.

Keywords:Perovskite;Light-emitting diode;Stability;Colour gamut;Ink-jet printing;Display

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[Referenced By]

[1] Grancini G, Roldan-Carmona C, Zimmermann I, Mosconi E, Lee X, et al., Nat. Commun., 8, 15684 (2017)

[2] Shin S, Yeom E, Yang W, Hur S, Kim M, Im J, Noh J, Seok S, Science, 356, 167 (2017)

[3] Kamar PV, ACS. Energy. Lett., 3, 28 (2018)

[4] Di Stasio F, Ramiro I, Bi Y, Christodoulou S, Stavrinadis A, Konstantatos G, Chem. Mater., 30, 6231 (2018)

[5] Li GR, Rivarola FWR, Davis NJLK, Bai S, Jellicoe TC, de la Pena F, Hou SC, Ducati C, Gao F, Friend RH, Greenham NC, Tan ZK, Adv. Mater., 28(18), 3528 (2016)

[6] Chiba T, Hoshi K, Pu YJ, Takeda Y, Hayashi Y, Ohisa S, Kawata S, Kido J, ACS Appl. Mater. Interfaces., 9, 18054 (2017)

[7] Shamsi J, Rastogi P, Caligiuri V, Abdelhady AL, Spirito D, Manna L, Krahne R, ACS Nano, 11, 10206 (2017)

[8] Saidaminov MI, Adinolfim V, Comin R, Abdelhady AL, Peng W, Dursun I, Yuan M, Hoogland S, Sargent EH, Bakr OM, Nat. Commun., 6, 8724 (2015)

[9] Miao J, Zhang F, J. Mater. Chem. C., 7, 1741 (2019)

[10] Zhang N, Fan Y, Wang K, Gu Z, Wang Y, Ge L, Xiao S, Song Q, Nat. Commun., 10, 1770 (2019)

[11] Protesescu L, Yakunin S, Bodnarchuk MI, Bertolotti F, Masciocchi N, Guagliardi A, Kovalenko MV, J. Am. Chem. Soc., 138(43), 14202 (2016)

[12] Wei Y, Cheng Z, Lin J, Chem. Soc. Rev., 48, 310 (2019)

[13] Krieg F, Ochsenbein ST, Yakunin S, Brinck S, Aellen P, Suess A, Clerc B, et al., ACS. Energy. Lett., 3, 641 (2018)

[14] Wang H, Zhang X, Wu Q, Cao F, Yang D, Shang Y, Ning Z, Zhang W, Zheng W, Yan Y, Kershaw SV, Zhang L, Rogach AL, Yang X, Nat. Commun., 10, 665 (2019)

[15] Han C, Tak Y, Ahn B, J. Soc. Inf. Display., 19, 190 (2011)

[16] Nagayama T, Yamamoto T, Nakamura T, Mizutani Y, ECS Trans., 50, 117 (2012)

[17] Kumar SN, John R, Lauer S, Daul B, J. Soc. Inf. Display., 46, 211 (2015)

[18] Jeong Y, Yu J, Shin K, Lee S, Yoon C, Lee S, Micro Nano. Syst. Lett., 7, 2 (2019)

[19] Schaer M, Nuesch F, Berner D, Leo W, Zuppiroli L, Adv. Funct. Mater., 11(2), 116 (2001)

[20] Chen S, Wu Q, Kong M, Zhao X, Yu Z, Jia P, Huang W, J. Mater. Chem. C., 1, 3508 (2013)

[21] Lee S, Song T, Cho S, Mat. Sci. Eng. B., 95, 24 (2002)

[22] Yin M, Pan T, Yu Z, Peng X, Zhang X, Xie W, Liu S, Zhang L, Org. Electron., 62, 407 (2018)

[23] Haverinen H, Dissertation (University of Oulu, Oulu 2009), Acta University Ouluensis C 351.

[24] Meyns M, Peralvarez M, Heuer-Jungemann A, Hertog W, Ibanez M, Nafria F, Genc A, Arbiol J, Kovalenko MV, Carreras J, Cabot A, Kanaras AG, ACS. Appl. Mater. Inter., 8, 19579 (2016)

[25] Zhang H, Wang X, Liao Q, Xu Z, Li H, Zheng L, Fu H, Adv. Funct., 27, 160438 (2017)

[26] Huang SQ, Li ZC, Kong L, Zhu NW, Shan AD, Li L, J. Am. Chem. Soc., 138(18), 5749 (2016)

[27] Zhong Q, Cao M, Hu H, Yang D, Chen M, Li P, Wu L, Zhang Q, ACS Nano, 12, 8579 (2018)

[28] Raja SN, Bekenstein Y, Koc MA, Fischer S, Zhang D, Lin L, Ritchie RO, Yang P, Alivisatos AP, ACS Appl. Mater. Interfaces., 8, 35523 (2016)

[29] Sun C, Zhang Y, Ruan C, Yin CY, Wang XY, Wang YD, Yu WW, Adv. Mater., 28(45), 10088 (2016)

[30] Kim H, Yoon D, Jang J, Lee D, Choi G, Chang J, Lee J, Lee D, Bae B, J. Am. Ceram. Soc., 138, 16478 (2016)

[31] Galisteo-Lopez JF, Anaya M, Calvo ME, Miguez H, J. Phys. Chem. Lett., 6, 2200 (2015)

[32] Tian Y, Merdasa A, Unger E, Abdellah M, Zheng K, McKibbin S, Mikkelsen A, Pullerits T, Yartsev A, Sundstrom V, Scheblykin IG, J. Phys. Chem. Lett., 6, 4171 (2015)

[33] Fu Y, Zhu H, Schrader AW, Liang D, Ding Q, Joshi P, Hwang L, Zhu XY, Jin S, Nano. Lett., 16, 1000 (2016)

[34] Li Y, Liu FZ, Waqas M, Leung TL, Tam HW, Lan XQ, Tu B, Chen W, Djurisic AB, He ZB, Small Methods, 2, 170038 (2018)

[35] Levchuk I, Osvet A, Tang X, Brandl M, Perea JD, Hoegl F, Matt GJ, Hock R, Batentschuk M, Brabec CJ, Nano. Lett., 17, 2765 (2017)

[36] Liu Z, Sun B, Liu X, Han J, Ye H, Shi T, Tang Z, Liao G, Nano-Micro. Lett., 10, 34 (2018)

[37] Holme I, Textiles Magazine, 31, 11 (2004)

[38] Shimoda T, Morii K, Seki S, Kiguchi H, MBS Bulletin, 28, 821 (2003)

[39] Magdassi S, World Scientific Publishing, pp. 19 Chapter 2, (2010).

[40] Choi S, Cho K, Namgoong J, Kim J, Yoo E, Lee W, Jung J, Choi J, Dyes Pigment., 163, 381 (2019)

[41] Salaoru I, Zhou Z, Morris P, Gibbons GJ, J. Appl. Polym. Sci., 133, 43572 (2016)

[42] Li C, Zang Z, Chen W, Hu Z, Tang X, Hu W, Sun K, Liu X, Chen W, Opt. Express., 24, 15071 (2016)

[43] Eperon GE, Stranks SD, Menelaou C, Johnston MB, Herz LM, Snaith HJ, Energy. Environ. Sci., 7, 982 (2014)

[44] Park D, Han J, Kim W, Jang H, Dyes Pigment., 149, 246 (2018)

[45] Kim S, Kim T, Kang M, Kwak SK, Yoo TW, Park LS, Yang I, Hwang S, Lee JE, Kim SK, Kim SW, J. Am. Chem. Soc., 134(8), 3804 (2012)

[46] Jo Y, Park S, J. ILASS-Korea, 15, 163 (2010)

[47] Yakunin S, Protesescu L, Krieg F, Bodnarchuk MI, Nedlcu G, Humer M, De Luca G, Fiebig M, Heiss W, Kovalenko MV, Nat. Commun., 6, 8056 (2015)