페난트롤린 유도체를 함유하는 형광 고분자 입자의 구리(II) 이온 감지

장근석; 이택승; Geunseok Jang; Taek Seung Lee

Polymer(Korea), Vol.44, No.2, 248-253, March, 2020

DOI10.7317/pk.2020.44.2.248 Export Citation

페난트롤린 유도체를 함유하는 형광 고분자 입자의 구리(II) 이온 감지

Detection of Cu(II) Ions by Fluorescent Polymer Particles Containing Phenanthroline Derivative

장근석, 이택승^†

충남대학교 유기소재·섬유시스템공학과

Geunseok Jang, and Taek Seung Lee^†

Organic and Optoelectronic Materials Laboratory, Department of Advanced Organic Materials and Textile System Engineering, Chungnam National University, Daejeon 34134, Korea

E-mail:

초록

형광 유기재료를 사용한 금속 이온 분석 방법은 많은 관심을 받고 있으며, 특히, 1,10-페난트롤린은 금속 이온과 결합을 통하여 감지에 뛰어난 성능을 보이는 것으로 알려져 있다. 이에 따라, 1,10-페난트롤린 유도체를 함유하는 고분자 입자를 제조하기 위하여 스타이렌과 1,10-페난트롤린 단량체를 공중합하여 형광 입자를 제조하였다. 이러한 형광 입자를 사용하여 수용액에서 구리(II) 이온 검출을 진행하였으며, 제조한 형광 고분자 입자는 구리(II) 이온에 대하여 형광이 변화되었다. 형광 변화를 이용한 구리(II) 이온 검출은 형광 턴-오프에 기반한 형광센서로 우수한 성능을 보였다.

Organic fluorescent sensors have received great attention for metal ions detection. Especially, it has been known that 1,10-phenanthroline is able to form a complex with metal ions. In this work, 1,10-phenanthroline derivative was copolymerized with styrene to fabricate particles, enabling detection of Cu(II) ions in aqueous medium. The polymer particles showed a high responsiveness to Cu(II) ions via fluorescence change. Recognition of Cu(II) ions via fluorescence change of the polymer particles exhibited a good performance as a fluorescent sensor based on fluorescence turn-off system.

Keywords:phenanthroline;fluorescence;sensors;Cu(II) ion detection

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[2] Hu JM, Wu T, Zhang GQ, Liu SY, Macromolecules, 45(9), 3939 (2012)

[3] Meier MAR, Schubert US, Chem. Commun., 4610 (2005).

[4] Zhang JJ, Cheng FF, Li JJ, Zhu JJ, Lu Y, Nano Today, 11(3), 309 (2016)

[5] Udhayakumaria D, Velmathia S, Sung YM, Wu SP, Sens. Actuators B-Chem., 198, 285 (2014)

[6] Rout K, Manna AK, Sahu M, Mondal J, Singh SK, Patra GK, RSC Adv., 9, 25919 (2019)

[7] Liang G,Cai Q, Zhu W, Xu Y, Qian X, Anal. Methods, 7, 4877 (2015)

[8] Chou CY, Liu SR, Wu SP, Analyst, 138, 3264 (2013)

[9] Zeng L, Miller EW, Pralle A, Isacoff EY, Chang CJ, J. Am. Chem. Soc., 128(1), 10 (2006)

[10] Giokas DL, Tsogas GZ, Vlessidis AG, Karayannis MI, Anal. Chem., 76, 1302 (2004)

[11] Tang X, Wang PY, Buchter G, Environments, 5, 95 (2018)

[12] Otero-Romani J, Moreda-Pineiro A, Bermejo-Barrera P, Martin-Esteban A, Talanta, 79, 723 (2009)

[13] Mandal A, Maity A, Bag S, Bhattacharya P, Das AK, Basak A, RSC Adv., 7, 7163 (2017)

[14] Dressler VL, Pozebon D, Curtius AJ, Spectroc. Acta Pt. B-Atom. Spectr., 53, 1527 (1998)

[15] Lv FT, Feng XL, Tang HW, Liu LB, Yang QO, Wang S, Adv. Funct. Mater., 21(5), 845 (2011)

[16] Wu JS, Wang PF, Zhang XH, Wu SK, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 65, 749 (2006)

[17] Yang S, Jiang W, Zhao F, Xu L, Xu Y, Gao B, Sun H, Du L, Tang Y, Cao F, Sens. Actuators B-Chem., 236, 386 (2016)

[18] Shao JN, Zhang Y, Cheung SM, Yang RH, Chan WH, Mo T, Li KA, Liu F, Anal. Chem., 77, 7294 (2005)

[19] Ding L, Wang S, Liu Y, Cao J, Fang Y, J. Mater. Chem. A, 1, 8866 (2013)

[20] Kaushik R, Ghosh A, Singh A, Gupta P, Mittal A, Jose DA, ACS Sens., 1, 1265 (2016)

[21] Pal S, Chatterjee N, Bharadwaj PK, RSC Adv., 4, 26585 (2014)

[22] Sanmartin-Matalobos J, Garcia-Deibe AM, Fondo M, Zarepour-Jevinani M, Dominguez-Gonzalezc MR, Bermejo-Barrera P, Dalton Trans., 46, 15827 (2017)

[23] Cetin MM, Hodson RT, Hart CR, Cordes DB, Findlater M, Casadonte DJ, Cozzolino AF, Mayer MF, Dalton Trans., 46, 6553 (2017)

[24] Afsar A, Distler P, Harwood LM, John J, Westwood J, Chem. Commun., 53, 4010 (2017)

[25] Afsar A, Laventine DM, Harwood LM, Hudsona MJ, Geist A, Chem. Commun., 49, 8534 (2013)

[26] Ng NS, Leverett P, Hibbs DE, Yang Q, Bulanadi JC, Wu MJ, Aldrich-Wright JR, Dalton Trans., 42, 3196 (2013)

[27] Saha ML, Neogi S, Schmittel M, Dalton Trans., 43, 3815 (2014)

[28] Galletta M, Scaravaggi S, Macerata E, Famulari A, Mele A, Panzeri W, Sansone F, Casnati A, Mariani M, Dalton Trans., 42, 16930 (2013)