화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.84, 52-71, April, 2020
DOI10.1016/j.jiec.2019.12.019  Export Citation
Experimental complemented with microscopic (electronic/atomic)-level modeling explorations of Laurus nobilis extract as green inhibitor for carbon steel in acidic solution
Ali Dehghani, Ghasem Bahlakeh†, Bahram Ramezanzadeh1, †, and Mohammad Ramezanzadeh1
  • Department of Chemical Engineering, Faculty of Engineering, Golestan University, Aliabad Katoul, Iran
  • 1Department of Surface Coatings and Corrosion, Institute for Color Science and Technology, P.O. Box 16765-654, Tehran, Iran
E-mail:,
In the present study, comprehensive research efforts were made to experimentally/theoretically examine the corrosion protection capability of Laurus nobilis leaves extract for carbon steel in an acidic medium composed of 1 M HCl. The experimental EIS results evidenced that upon steel exposure to a corrosive electrolyte containing 400 ppm L. nobilis leaves extract the maximum protection performance of 92% was obtained after 2.5 h. The experiments of potentiodynamic polarization proposed a mixed-type anodic/cathodic anti-corrosion action along with small cathodic prevalence. The electronic features established by the DFT approach highlighted that the surface adsorption mechanism could be described by donor-acceptor interactions.
Keywords:Laurus nobilis leaves extract;EIS;Potentiodynamic polarization;SEM;AFM;MC/MD/DFT
  1. Fatima S, Sharma R, Asghar F, Kamal A, Badshah A, Kraatz HB, J. Ind. Eng. Chem., 76, 374 (2019)
  2. Othman NK, Yahya S, Ismail MC, J. Ind. Eng. Chem., 70, 299 (2019)
  3. Obot IB, Solomon MM, Umoren SA, Suleiman R, Elanany M, Alanazi NM, Sorour AA, J. Ind. Eng. Chem., 79, 1 (2019)
  4. Alvarez PE, Fiori-Bimbi MV, Neske A, Brandan SA, Gervasi CA, J. Ind. Eng. Chem., 58, 92 (2018)
  5. Tan B, Zhang S, Li W, Zuo X, Qiang Y, Xu L, Hao J, Chen S, J. Ind. Eng. Chem., 77, 449 (2019)
  6. Verma C, Olasunkanmi LO, Ebenso EE, Quraishi MA, Obot IB, J. Phys. Chem. C, 120, 11598 (2016)
  7. Singh P, Ebenso EE, Olasunkanmi LO, Obot IB, Quraishi MA, J. Phys. Chem. C, 120, 3408 (2016)
  8. Olasunkanmi LO, Obot IB, Kabanda MM, Ebenso EE, J. Phys. Chem. C, 119, 16004 (2015)
  9. Lyu B, Liu H, Li P, Gao D, Ma J, J. Ind. Eng. Chem., 80, 411 (2019)
  10. Asaad MA, Sarbini NN, Sulaiman A, Ismail M, Huseien GF, Majid ZA, Raja PB, J. Ind. Eng. Chem., 63, 139 (2018)
  11. Fouda AS, Ismail MA, Temraz AM, Abousalem AS, New J. Chem., 43, 768 (2019)
  12. Abousalem AS, Ismail MA, Fouda AS, J. Mol. Liq., 276, 255 (2019)
  13. Dohare P, Ansari KR, Quraishi MA, Obot IB, J. Ind. Eng. Chem., 52, 197 (2017)
  14. Ramezanzadeh M, Sanaei Z, Bahlakeh G, Ramezanzadeh B, J. Mol. Liq., 256, 67 (2018)
  15. Ghames A, Douadi T, Issaadi S, Sibous L, Alaoui KI, Taleb M, Chafaa S, Int. J. Electrochem. Sci., 12, 4867 (2017)
  16. Kumar A, Trivedi M, Sharma RK, Singh G, New J. Chem., 41, 8459 (2017)
  17. Mehdipour M, Ramezanzadeh B, Arman SY, J. Prog. Color. Color Coat., 8, 69 (2015)
  18. Verma C, Olasunkanmi LO, Quadri TW, Sherif ESM, Eb EE, J. Phys. Chem. C, 122, 11870 (2018)
  19. Verma C, Haque J, Ebenso EE, Quraishi M, Results Phys., 9, 100 (2018)
  20. Shah AM, Rahim AA, Ibrahim MNM, Hussin MH, Int. J. Electrochem. Sci., 12, 9017 (2017)
  21. Bourazmi H, Tabyaoui M, Hattabi L, El Aoufir Y, Taleb M, J. Mater. Environ. Sci., 9, 928 (2018)
  22. Nofrizal S, Rahim AA, Saad B, Raja PB, Shah AM, Yahya S, Metall. Mater. Trans. A-Phys. Metall. Mater. Sci., 43, 1382 (2012)
  23. Afia L, Salghi R, Zarrouk A, Zarrok H, Bazzi EH, Hammouti B, Zougagh M, Trans. Indian Inst. Met., 66, 43 (2013)
  24. Alibakhshi E, Ramezanzadeh M, Bahlakeh G, Ramezanzadeh B, Mahdavian M, Motamedi M, J. Mol. Liq., 255, 185 (2018)
  25. Haldhar R, Prasad D, Saxena A, Kumar R, Sustain. Chem. Pharm., 9, 95 (2018)
  26. Saxena A, Prasad D, Haldhar R, Singh G, Kumar A, J. Environ. Chem. Eng., 6, 694 (2018)
  27. Haldhar R, Prasad D, Saxena A, Singh P, Mater. Chem. Front., 2, 1225 (2018)
  28. Solomon MM, Gerengi H, Umoren SA, Essien NB, Essien UB, Kaya E, Carbohydr. Polym., 181, 43 (2018)
  29. Conforti F, Statti G, Uzunov D, Menichini F, Biol. Pharm. Bull., 29, 2056 (2006)
  30. Fiorini C, Fouraste I, David B, Bessiere J, Flavour Fragr. J., 12, 91 (1997)
  31. Jemaa JMB, Tersim N, Toudert KT, Khouja ML, J. Stored Prod. Res., 48, 97 (2012)
  32. Dehghani A, Bahlakeh G, Ramezanzadeh B, Ramezanzadeh M, J. Taiwan Inst. Chem. Eng., 102, 349 (2019)
  33. Becke AD, J. Chem. Phys., 98, 5648 (1993)
  34. Kohn W, Sham LJ, Phys. Rev., 140, A1133 (1965)
  35. Tomasi J, Mennucci B, Cammi R, Chem. Rev., 105(8), 2999 (2005)
  36. Breneman CM, Wiberg KB, J. Comput. Chem., 11, 361 (1990)
  37. Saha SK, Ghosh P, Hens A, Murmu NC, Banerjee P, Physica E, 66, 332 (2015)
  38. Saha SK, Murmu M, Murmu NC, Banerjee P, J. Mol. Liq., 224, 629 (2016)
  39. Ramezanzadeh M, Bahlakeh G, Sanaei Z, Ramezanzadeh B, Appl. Surf. Sci., 463, 1058 (2019)
  40. Salarvand Z, Amirnasr M, Talebian M, Raeissi K, Meghdadi S, Corrosion Sci., 114, 133 (2017)
  41. Srivastava V, Haque J, Verma C, Singh P, Lgaz H, Salghi R, Quraishi M, J. Mol. Liq., 244, 340 (2017)
  42. Martyna GJ, Klein ML, Tuckerman M, J. Chem. Phys., 97, 2635 (1992)
  43. Gupta RK, Malviya M, Verma C, Quraishi MA, Mater. Chem. Phys., 198, 360 (2017)
  44. Mobin M, Aslam R, Process. Saf. Environ., 114, 279 (2018)
  45. Al-Azawi KF, Mohammed IM, Al-Baghdadi SB, Salman TA, Issa HA, Al-Amiery AA, Gaaz TS, Kadhum AAH, Results Phys., 9, 278 (2018)
  46. Kamal C, Sethuraman MG, Ind. Eng. Chem. Res., 51(31), 10399 (2012)
  47. Zhang K, Yang W, Yin X, Chen Y, Liu Y, Le J, Xu B, Carbohydr. Polym., 181, 191 (2018)
  48. Yadav DK, Quraishi MA, Ind. Eng. Chem. Res., 51(46), 14966 (2012)
  49. Xavier Stango SA, Vijayalakshmi U, J. Asian Ceram. Soc., 6, 20 (2018)
  50. Tasic ZZ, Mihajlovic MBP, Radovanovic MB, Simonovic AT, Antomijevic MM, J. Mol. Struct., 1159, 46 (2018)
  51. Sherif EM, Erasmus RM, Comins JD, Electrochim. Acta, 55(11), 3657 (2010)
  52. Hamani H, Douadi T, Daoud D, Al-Noaimi M, Rikkouh RA, Chafaa S, J. Electroanal. Chem., 801, 425 (2017)
  53. Olasunkanmi LO, Moloto BP, Obot IB, Ebenso EE, J. Mol. Liq., 252, 62 (2018)
  54. Haque J, Srivastava V, Verma C, Quraishi M, J. Mol. Liq., 225, 848 (2017)
  55. Li WH, He Q, Pei CL, Hou BR, Electrochim. Acta, 52(22), 6386 (2007)
  56. Abeng FE, Idim VD, World Sci. News, 98, 89 (2018)
  57. Afzalkhah M, Masoum S, Behpour M, Naeimi H, Reisi-Vanani A, Ind. Eng. Chem. Res., 56(32), 9035 (2017)
  58. Al-Ahmary KM, Mekheimer RA, Al-Enezi MS, Hamada NM, Habeeb MM, J. Mol. Liq., 249, 501 (2018)
  59. Al-Sabagh AM, El Basiony NM, Sadeek SA, Migahed MA, Desalination, 437, 45 (2018)
  60. Zeino A, Abdulazeez I, Khaled M, Jawich MW, Obot IB, J. Mol. Liq., 250, 50 (2018)
  61. Tabatabaei majd M, Shahrabi R, Ramezanzadeh B, Bahlakeh G, J. Taiwan Inst. Chem. Eng., 96, 610 (2019)
  62. Anupama K, Joseph A, J. Bio Tribo Corros., 4, 1 (2018)
  63. Anzar N, Mirza MA, Anwer K, Khuroo T, Alshetaili AS, Alshahrani SM, Meena J, Hasan N, Talegaonkar S, Panda AK, J. Mol. Liq., 249, 609 (2018)
  64. Ashassi-Sorkhabi H, Shaabani B, Seifzadeh D, Appl. Surf. Sci., 239(2), 154 (2005)
  65. Bahrami M, Hosseini S, Pilvar P, Corrosion Sci., 52, 2793 (2010)
  66. Mobin M, Basik M, Aslam J, J. Mol. Liq., 263, 174 (2018)
  67. Bahlakeh G, Ramezanzadeh B, Dehghani A, Ramezanzadeh M, J. Mol. Liq., 283, 174 (2019)
  68. Senatore E, Taleb W, Owen J, Hua Y, Gomes JP, Barker R, Neville A, Wear, 404, 143 (2018)
  69. Majd MT, Shahrabi T, Ramezanzadeh B, J. Alloy. Compd., 783, 952 (2019)
  70. Khadom AA, Abd AN, Ahmed NA, J. Bio Tribo Corros., 4, 17 (2018)
  71. Saxena A, Prasad D, Haldhar R, Singh G, Kumar A, J. Mol. Liq., 258, 89 (2018)
  72. Obot I, Obi-Egbedi N, Umoren S, Ebenso E, Int. J. Electrochem. Sci, 5, 994 (2010)
  73. Haque J, Verma C, Srivastava V, Quraishi M, Ebenso EE, Results Phys., 9, 1481 (2018)
  74. Doner A, Solmaz R, Ozcan M, Kardas G, Corrosion Sci., 53, 2902 (2011)
  75. Zehra S, Mobin M, Aslam J, Parveen M, J. Adhes. Sci. Technol., 32(3), 317 (2018)
  76. Singh AK, Ind. Eng. Chem. Res., 51(8), 3215 (2012)
  77. Krishnegowda PM, Venkatesha VT, Krishnegowda PKM, Shivayogiraju SB, Ind. Eng. Chem. Res., 52(2), 722 (2013)
  78. Gopi D, Sherif EM, Manivannan V, Rajeswari D, Surendiran M, Kavitha L, Ind. Eng. Chem. Res., 53(11), 4286 (2014)
  79. Farag AA, Ismail AS, Migahed MA, Egypt. J. Pet., 27, 1187 (2018)
  80. Satoh H, Desalination, 97, 45 (1994)
  81. Heggs P, Chem. Eng., 49 (2001).
  82. Chauhan DS, Ansari K, Sorour A, Quraishi M, Lgaz H, Salghi R, Int. J. Biol. Macromol., 107, 1747 (2018)
  83. Saha SK, Dutta A, Ghosh P, Sukul D, Banerjee P, Phys. Chem. Chem. Phys., 18, 17898 (2016)
  84. Saha SK, Banerjee P, RSC Adv., 5, 71120 (2015)
  85. Gerengi H, Sahin HI, Ind. Eng. Chem. Res., 51, 780 (2011)
  86. Zhang Z, Ba H, Wu Z, Zhu Y, Constr. Build. Mater., 198, 288 (2019)
  87. Abdulmajid A, Hamidon TS, Rahim AA, Hussin MH, Mater. Res. Express, 6, 106579 (2019)
  88. Rabizadeh T, Khameneh Asl S, Mater. Corros., 70, 738 (2019)
  89. Banerjee S, Srivastava V, Singh M, Corrosion Sci., 59, 35 (2012)
  90. Haruna K, Obot I, Ankah N, Sorour A, Saleh T, J. Mol. Liq., 264, 515 (2018)
  91. Fernandes CM, Alvarez LX, dos Santos NE, Barrios ACE, Ponzio EA, Corrosion Sci., 149, 185 (2019)
  92. Sadeghi Erami R, Amirnasr M, Meghdadi S, Talebian M, Farrokhpour H, Raeissi K, Corrosion Sci., 151, 190 (2019)
  93. Olasunkanmi LO, Ebenso EE, J. Colloid Interface Sci., 561, 104 (2020)