화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.83, 235-246, March, 2020
DOI10.1016/j.jiec.2019.11.033  Export Citation
Preparation of polyaminated Fe3O4@chitosan core-shell magnetic nanoparticles for efficient adsorption of phosphate in aqueous solutions
Chun-Chieh Fu1, Hai Nguyen Tran2, Xing-Han Chen1, and Ruey-Shin Juang1, 3, †
  • 1Department of Chemical and Materials Engineering, Chang Gung University, Guishan, Taoyuan, 33302, Taiwan
  • 2Institute of Fundamental and Applied Sciences, Duy Tan University, Ho Chi Minh City, 700000, Vietnam
  • 3Division of Nephrology, Department of Internal Medicine, Chang Gung Memorial Hospital, Linkou, Taiwan
E-mail:
In this study, novel polyethylenimine (PEI)-grafted chitosan (CS) core-shell (called as Fe3O4/CS/PEI) magnetic nanoparticles were synthesized and applied for adsorbing phosphate in water. The magnetic and physicochemical properties of as-synthesized nanoparticles were first analyzed by means of a superconducting quantum interference device, X-ray diffractometer, X-ray photoelectron spectroscope, Fourier-transform infrared spectroscope, transmission electron microscope, zeta potential analyzer, and nitrogen sorptiometer. The followed experiments indicated that the amount of phosphate adsorbed increased with increasing equilibrium pH to near 4.0 and then decreased when the pH was further increased. The adsorption isotherms of phosphate on Fe3O4/CS/PEI particles were well fit by the Langmuir equation, and its maximum adsorption was 48.2 mg g-1 at an equilibrium pH of 3.0 and 25 °C. The primary mechanism for phosphate adsorption on Fe3O4/CS/PEI particles was electrostatic attraction. The preferential adsorption of phosphate in the presence of other excess anions including chloride, nitrate, carbonate, and sulfate was presented. Under the conditions studied, more than 90% of phosphate was desorbed from the laden Fe3O4/CS/PEI particles by 0.05 mol L-1 of NaOH solution. The remained adsorption efficiency obtained in the five-cycle reusability tests has demonstrated the promising application potential of Fe3O4/CS/PEI particles.
Keywords:Adsorption;Chitosan;Core-shell structure;Magnetic nanoparticles;Phosphate removal;Polyethylenimine
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