A sol gel method was used to synthesize barium, lanthanum, and tungsten-based samples doped with praseodymium Ba(La1-xPrx)(2)WO7, where x = 0.005 divided by 0.05. The morphological and elemental analyses of the samples were carried out by electron probe microanalysis. A full-profile refinement of the crystal structure of the compounds belonging to the monoclinic system with the space group P112(1)/b was carried out. Using the adiabatic calorimetry method, the heat capacity of the samples was measured and the thermodynamic functions in the range of 5-320 K were found. In the heat capacity of the samples below 15 K, anomalies were detected and the excessive and lattice heat capacities were determined.