Lithium-sulfur (Li-S) batteries are considered as a next-generation energy storage solution thanks to the dramatic increase in their energy density and the accompanying low fabrication cost. Nonetheless, their practical applications have been hampered by critical challenges such as cycling instability, low sulfur utilisation and efficiency. Here, the interfacial growth of Ni(OH)(2)-encapsulated sulfur nanoparticles in a reduced graphene oxide free-standing matrix as Li S cathodes has been highlighted, along with a detailed application investigation of the sandwich foam structure in Li-S batteries. Compared to sulfur composites based solely on a graphene host (S@rGO), this composite foam cathode could provide significant improvements in specific capacity and long-cycle stability with the effective confinement and promoted conversion of lithium polysulfides. Moreover, the sandwich foam composite cathode exhibits a high specific capacity of 1189 mA h g(-1) (0.1 C), better rating performance (691 mA h g(-1) at 2 C) and remarkable cycling stability, retaining 81% of the initial capacity after 200 cycles of charge -discharge at 0.2 C. Furthermore, Ni(OH)(2) wrapping at the cathode-electrolyte interface offers vastly improved polysulfide shuttle suppression, which provides a new cathode encapsulation method for further developments of advanced Li-S cathodes. (C) 2019 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.